CALABRIAN CORP -- COPPER SULFATE -- 6810-00N052308
===================== Product Identification ===================== Product ID:COPPER SULFATE MSDS Date:03/01/1991 FSC:6810 NIIN:00N052308 === Responsible Party === Company Name:CALABRIAN CORP Address:15,600 J F KENNEDY BLVD SUITE 570 City:HOUSTON State:TX ZIP:77032 Country:US Info Phone Num:713-590-5007 Emergency Phone Num:800-424-9300 (CHEMTREC) CAGE:CALAB === Contractor Identification === Company Name:CALABRIAN CORP Address:1445 NORTH LOOP WEST STE 800 Box:City:HOUSTON State:TX ZIP:77008 Country:US Phone:713-880-9981 CAGE:CALAB ============= Composition/Information on Ingredients ============= Ingred Name:COPPER (II) SULFATE, PENTAHYDRATE (1:1:5); COPPER SULFATE PENTAHYDRATE CAS:7758-99-8 RTECS #:GL8900000 Fraction by Wt: 99%+ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT: REMAINS (AT LEAST 15-20 MIN). GET MED ATTN IMMED. INGEST: IF CONSCIOUS GIVE 2 - 4 GLASSES OF WATER/MILK (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: & REMOVE BY GASTRIC LAVAGE UNLESS ALREADY VOMITING. GET MED ATTN IMMED. NEVER GIVE ANYTHING BY MOUTH TO (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: AN UNCONSCIOUS PERSON. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (RAT) 300 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHAL: MAY CAUSE IRRIT OF UPPER RESP TRACT. MAY ALSO DMG LIVER, KIDNEYS & RPTD INHAL MAY CAUSE CNS EXCITATION FOLLOWED BY DEPRESS. RPTD INHAL OF DUST/MIST MAY CAUSE ULCERATION & PERFORATION OF NASAL S EPTUM. SKIN: CNTCT CAUSES IRRIT & ITCHING. SENSIT MAY OCCUR W/ITCHING & NECROSIS. EYES: MAY CAUSE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: CONJ, CORNEAL ULCERATION & EDEMA. RPTD/PRLNG CNTCT MAY CAUSE CONJ, CORNEAL ULCERATION & TURBIDITY. INGEST: MAY CAUSE SALIVATION, NAUS, VOMIT, GASTRIC PAIN, LOCAL CORR & HEMORR, BLUE DISCOLOR ATION OF GUMS & TONGUE, HEMOLYTIC ANEMIA, COLIC & DIARR W/BLOODY STOOLS. LIVER & KIDNEY DMG MAY OCCUR W/POSS (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR IMMED. IF BRTHG HAS STOPPED GIVE ARTF RESP. IF BRTHG IS DFCLT O*2 MAY BE GIVEN BY QUALIFIED PERS. KEEP AFFECTED PERSON WARM & QUIET. GET MED ATTN IMMED. SKIN: REMOVE CONTAMD CLTHG & SHOES IMMED. WASH AFFECTED AREA W/SOAP/MILD DETERGENT & LG AMTS OF WATER UNTIL NO EVID OF CHEM REMAINS (APPPROX 15-20 MIN). GET MED ATTN IMMED. WASH CLTHG BEFORE REUSE. DISCARD (SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point:NOT FLAMMABLE Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, HALON, WATER SPRAY OR STANDARD FOAM. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:MAY RELEASE TOXIC FUMES OF SULFUR OXIDES UPON DECOMPOSITION OF MATERIAL. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE BEYOND SPILL OR LEAK TO PVNT MATL FROM ENTERING SEWERS & WATERWAYS. DO NOT USE BARE HANDS TO CLEAN SPILL. CAREFULLY SWEEP INTO CLEAN CNTNRS FOR DISPOSAL. FOR SPILLS ABOVE 10 LBS: REPORT SPILL TO APPROP EMER RESPONSE AGENCIES. FOLLOW SPILL PROC. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED HIGH EFFICIENCY DUST RESPIRATOR WITH FULL FACE PLATE. Ventilation:PROVIDE LOCAL EXHAUST VENTILATION TO MEET RECOMMENDED EXPOSURE LIMITS. Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:DUST-RESISTANT SAFETY GOGGLES. Other Protective Equipment:IMPERVIOUS PROTECTIVE CLTHG TO PREVENT SKIN CONTACT. EYE WASH FOUNTAIN & SAFETY SHOWER SHOULD BE AVAILABLE TO WORK AREA. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health PH: 4-6 (1% IN WATER). EFTS OF OVEREXP: SOMNOLENCE & COMA. DEATH MAY OCCUR FROM CIRCULATORY FAILURE. CHRONIC COPPER POISONING MAY OCCUR IN INDIVIDUALS AFFLICTED W/WILSON'S DISEASE. FIRST AID PROC: CON TAMD SHOES. EYES: FLUSH IMMED W/LG AMTSOF WATER, OCCAS LIFTING UPPER & LOWER LIDS, UNTIL NO EVID OF CHEM (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:302F,150C Melt/Freeze Pt:M.P/F.P Text:230F,110C Spec Gravity:2.28 pH:SUPDAT Solubility in Water:SOLUBLE, 32% Appearance and Odor:BLUE TO CLEAR CRYSTALS, GRANULES OR POWDER; NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTS VIGOROUSLY WITH HYDROXYLAMINE. Stability Condition to Avoid:HEATING TO DECOMPOSITION AND STORAGE WITH INCOMPATIBLE MATERIALS. Hazardous Decomposition Products:THERMAL DECOMPOSITION RESULTS IN TOXIC OXIDES OF SULFUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL ACCORDING TO LOCAL, STATE AND FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.