STAUFFER CHEMICAL CO. -- SULFUR -- 6810-00-282-9709
===================== Product Identification ===================== Product ID:SULFUR MSDS Date:01/01/1987 FSC:6810 NIIN:00-282-9709 === Responsible Party === Company Name:STAUFFER CHEMICAL CO. Address:SPECIALTY CHEMICAL DIV City:WESTPORT State:CT ZIP:06880-6240 Country:US Info Phone Num:203-226-6602 Emergency Phone Num:203-226-6602 /CHEMTREC 800-424-9300 CAGE:8F554 === Contractor Identification === Company Name:CHEMICAL COMMODITIES AGENCY, INC. Address:27447 PACIFIC STREET Box:City:HIGHLAND State:CA ZIP:92346-2640 Country:US Phone:909-864-2310 CAGE:60777 Company Name:STAUFFER CHEMICAL CO SPECIALTY CHEMICAL DIVISION Address:NYALA FARMS RD Box:City:WESTPORT State:CT ZIP:06880 Country:US Phone:203-226-6602/CHEMTREC 800-424-9300 CAGE:8F554 ============= Composition/Information on Ingredients ============= Ingred Name:SULFUR CAS:7704-34-9 RTECS #:WS4250000 Fraction by Wt: OVER 99% Other REC Limits:15 MG/CUM NUIS. DUST OSHA PEL:NONE ESTABLISHED ACGIH TLV:NONE ESTABLISHED Ingred Name:EXPOSURE LIMITS FOR SULFUR DIOXIDE (PRODUCED BY FIRE) RTECS #:9999999ZZ OSHA PEL:5 PPM ACGIH TLV:2 PPM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:SULFUR IS ESSENTIALLY NON-TOXIC. IT IS A MECHANICAL IRRITANT AS A DUST. Effects of Overexposure:MILD TO MODERATE IRRITATION, ALL EXPOSURES. Medical Cond Aggravated by Exposure:HMIS: PRE-EXISTING RESPIRATORY CONDITIONS IF DUST IS BREATHED. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH WITH WATER. SKIN: WASH WITH SOAP AND WATER. INHALED: REMOVE TO FRESH AIR. INGESTED: INDUCE VOMITING,CONSULT A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:405F/207C Autoignition Temp:Autoignition Temp Text:511F Extinguishing Media:WATER FOG. DO NOT USE STREAM AS THIS CAN RAISE DUST CAUSING EXPLOSION. SULFUR WILL REKINDLE UNTIL COOLED BELOW 310F/154C Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS. EXCLUDE UNPROTECTED INDIVIDUALS. Unusual Fire/Explosion Hazard:SULFUR BURNS EMITTING TOXIC CHOKING FUMES. SULFUR DUST IN AIR PRESENTS EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP/SHOVEL MATERIAL INTO CONTAINERS FOR RECOVERY OR DISPOSAL. DO NOT GENERATE DUST DURING CLEAN-UP. WEAR APPROPRIATE PROTECTIVE EQUIPMENT. Neutralizing Agent:NONE ====================== Handling and Storage ====================== Handling and Storage Precautions:FOLLOW NORMAL INDUSTRIAL HYGIENE PROCEDURES. Other Precautions:GUARD AGAINST ASPIRATION OF DUST INTO AIR. WEAR SAFETY GOGGLES, SELF-CONTAINED BREATHING APPARATUS & MASK. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED DUST RESPIRATOR IF OVER DUST TLV Ventilation:PROVIDE GENERAL/LOCAL EXHAUST TO MAINTAIN UNDER TLV Protective Gloves:NONE Eye Protection:SAFETY GLASSES Other Protective Equipment:NONE Work Hygienic Practices:STANDARD INDUSTRIAL HYGIENE. Supplemental Safety and Health UPDATE PER UNDATED MSDS RECEIVED 8JAN88. ================== Physical/Chemical Properties ================== HCC:F8 Boiling Pt:B.P. Text:831F/444C Melt/Freeze Pt:M.P/F.P Text:230F/110C Vapor Pres:0.0001 Solubility in Water:INSOLUBLE Appearance and Odor:YELLOW POWDER,LUMPS,OR CRYSTALS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS SUCH AS NITRITES AND CHLORATES. ALSO ALKALI Stability Condition to Avoid:DUST Hazardous Decomposition Products:BURNING PRODUCES TOXIC CHOKING SULFUR DIOXIDE. LCLO HUMAN: 1000 PPM 10 MIN. PULMONARY DISTRESS SYMPTOMS MAY BE DELAYED ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF SCRAP IN MANNER I/A/W FEDERAL,STATE,LOCAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.