ASHLAND CHEMICAL INC -- DENATURED ALCOHOL 70% -- 6810-00F030372
===================== Product Identification ===================== Product ID:DENATURED ALCOHOL 70% MSDS Date:09/12/1991 FSC:6810 NIIN:00F030372 === Responsible Party === Company Name:ASHLAND CHEMICAL INC Box:2219 City:COLUMBUS State:OH ZIP:43216-2219 Country:US Info Phone Num:614-889-3333 Emergency Phone Num:800-274-5263 CAGE:34897 === Contractor Identification === Company Name:ASHLAND CHEMICAL CO Box:2219 City:COLUMBUS State:OH ZIP:43216-2219 Country:US Phone:614-790-3333/800-274-5263 CAGE:34897 ============= Composition/Information on Ingredients ============= Ingred Name:METHANOL (METHYL ALCOHOL), COLUMBIAN SPIRITS CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 3% Other REC Limits:200 PPM OSHA PEL:260 MG/CUM ACGIH TLV:262 MG/CUM (SKIN) EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHANOL (ETHYL ALCOHOL), TECSOL, ALCOHOL CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: >60% Other REC Limits:1900 MG/CUM OSHA PEL:1000 PPM ACGIH TLV:1000 PPM Ingred Name:HEXONE, METHYL ISOBUTYL KETONE (MIBK), 4-METHYL-2-PENTANONE CAS:108-10-1 RTECS #:SA9275000 Fraction by Wt: 1% Other REC Limits:50 PPM OSHA PEL:410 MG/CUM ACGIH TLV:205 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EYES: MODERATE IRRITATION & DAMAGE. INHALATION: NASAL & RESPIRATORY IRRITATION, CENTRAL NERVOUS SYSTEM EFFECTS. INGESTION: LIVER ABNORMALITIES, GASTROINTESTINAL IRRITATION. SKIN: SLIGHT IRRITATION & A BSORPTION. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: REDNESS & TEARING. INHALATION: DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE, & POSSIBLE UNCONSCIOUSNESS. INGESTION: NAUSEA, VOMITING & DIARRHEA. METHANOL MAY CAUSE METABOLIC ACIDOSIS, VISUCAL DISTURBANCES & BLINDNESS. ======================= First Aid Measures ======================= First Aid:SKIN: WASH W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING. EYES: FLUSH W/PLENTY OF WATER. INGESTION: IMMEDIATELY DRINK 2 GLASSES OF WATER & INDUCE VOMITING BY GIVING IPECAC SYRUP/PLACING FINGER AT BACK OF THROAT. NEVER GIVE ANYTHING BY MOUTHIF UNCONSCIOUS. INHALATION: REMOVE TO FRESH AIR. IF DIFFICULTY BREATHING, GIVE OXYGEN. IF BREATHING STOPS, GIVE ARTIFICIAL RESPIRATION. KEEP WARM/QUIET. (SUPP) ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:55-75F Lower Limits:1.4% Extinguishing Media:ALCOHOL FOAM, CO2 OR DRY CHEMICAL Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS W/FULL FACEPIECE OPERATED IN POSITIVE PRESSURE DEMAND MODE. Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR & MAY TRAVEL ALONG GROUND/MOVED BY VENTILATION & IGNITED BY IGNITION SOURCE. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB ON VERMICULITE/FLOOR ABSORBENT/OTHER ABSORBENT. ELIMINATE ALL IGNITION SOURCES. WEAR PROTECTIVE EQUIPMENT. STOP SPILL AT SOURCE. PREVENT FROM ENTERING ANY WATER SYSTEMS. PREVENT FROM SPREADING. PUMP/VACUUM TO CLEAN CONTAINERS FOR RECOVERY. ====================== Handling and Storage ====================== Handling and Storage Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED, SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR, LIQUID, &/OR SOLID). Other Precautions:NEVER USE WELDING/CUTTING TORCH ON/NEAR DURM (EVEN EMPTY) CAN IGNITE EXPLOSIVELY. 5 GALLON PARTS & LARGER CONTAINERS INCLUDING TANK CARS/TRUCKS SHOULD BE GROUNDED/BONDED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR. ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE. Ventilation:SUFFICIENT MECHANICAL (GENERAL &/OR LOCAL EXHAUST) TO MAINTAIN EXPOSURE BELOW TLV'S. Protective Gloves:RESISTANT (NEOPRENE OR NITRILE RUBBER) Eye Protection:CHEMICAL SPLASH GOGGLES, SAFETY GLASSES Other Protective Equipment:IMPERVIOUS CLOTHING & BOOTS Supplemental Safety and Health NOTE TO PHYSICIAN: THIS PRODUCT CONTAINS METHANOL. METHANOL IS METABOLIZED TO FORMALDEHYDE & FORMIC ACID. TOXIC SYMPTOMS MAY BE DELAYED FROM 6 TO 30 HOURS FOLLOWING INGESTION. ETHANOL COMPETES FOR THE SAME METABOLIC PATHWAY & HAS BEEN USEDAS AN ANTIDOTE. METHANOL IS EFFECTIVELY REMOVED BY HEMODIALYSIS. ================== Physical/Chemical Properties ================== Vapor Pres:97.68 Vapor Density:>1 Spec Gravity:<1 Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Hazardous Decomposition Products:CO2, CO, VARIOUS HYDROCARBONS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.