AIR LIQUID AMERICA CORP -- ARGON -- 6830-01-103-9103
===================== Product Identification ===================== Product ID:ARGON MSDS Date:01/30/1997 FSC:6830 NIIN:01-103-9103 === Responsible Party === Company Name:AIR LIQUID AMERICA CORP Address:2700 POST OAK DR City:HOUSTON State:TX ZIP:77056-8229 Country:US Info Phone Num:716-868-0440 Emergency Phone Num:800-424-9300 (CHEMTREC) CAGE:24274 === Contractor Identification === Company Name:AIR LIQUID AMERICA CORP Address:2700 POST OAK DR Box:City:HOUSTON State:TX ZIP:77056-8229 Country:US Phone:716-868-0440 CAGE:24274 ============= Composition/Information on Ingredients ============= Ingred Name:ARGON CAS:7440-37-1 RTECS #:CF2300000 Fraction by Wt: 99.98% OSHA PEL:N/K ACGIH TLV:ASPHYXIANT Ingred Name:IMPURITIES; (MAXIMUM IMPURITIES) Fraction by Wt: <0.02% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:KNOWN ADVERSE HLTH EFTS ASSOC W/CHRONIC EXPOS TO ARGON. TARGET ORGS:RESP SYS. TOX INFO:ANIMAL STUDIES (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:CONCERN DEFICIENCY OF/NARC EFTS OF VARIOUS PRESSURES OF ARGON, EFTS OF INCR ARGON PRESS ON CNS & DECOMP SICKNESS. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:OXYG. ONLY TRAINED PERS SHOULD ADMIN SUPP OXYG. VICTIM(S) MUST BE TAKEN FOR MED ATTN. RESCUERS (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:SHOULD BE TAKEN FOR MED ATTN, IF NEC. TAKE COPY OF LBL & MSDS TO MD/OTHER HLTH PROFESSIONAL W/VICTIM(S). (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:NOTE TO MD:TREAT SYMPTOMS & REDUCE OVEREXPOSURE. RTECS #:9999999ZZ Ingred Name:SPILL PROC:B:NIOSH APPRVD SCBA. LOCATE & SEAL SOURCE OF LEAKING GAS. ALLOW GAS, WHICH IS HVR/AIR TO DISSIPATE. (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:MONITOR SURROUND AREA FOR OXYG LEVELS. ATM MUST HAVE AT LST 19.5% OXYG BEFORE PERS CAN BE ALLOWED IN AREA (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:W/OUT NIOSH APPRVD SCBA. IF LEAKING INCIDENTALLY FROM CYL/ITS VALVE, CONT YOUR SUPPLIER. RTECS #:9999999ZZ Ingred Name:OTHER PREC:CLEAR OF MATLS WHICH CAN BURN. DO NOT ALLOW AREA WHERE CYLS ARE STORED TO EXCEED 52C(125F). STORE (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:AWAY FROM PROCESS & PRODUCTION AREAS, AWAY FROM ELEVATORS, BLDG & ROOM EXITS/MAIN AISLES LEADING TO (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:EXITS. PROT CYLS AGAINST PHYSICAL DMG. USE CHECK VALVE/OTHER PROT DEVICE IN DISCHARGE LINE TO PVNT HAZ (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:BACKFLOW. NEVER TAMPER W/PRESS RELIEF VALVES & CYLS. KEEP SMALLEST AMT NEC ON-SITE AT ANY ONE TIME. FULL (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:& EMPTY CYLS SHOULD BE SEGREGATED. USE FIRST-IN, FIRST-OUT INVENTORY SYS TO PVNT FULL CNTNRS FROM BEING (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:STORED FOR LONG PERIODS OF TIME. COMPRESSED GASES CAN PRESENT SIGNIFICANT SFTY HAZS. FOLLOWING RULES ARE (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:APPLIC TO WORK SITUATIONS IN WHICH CYLS ARE BEING USED: BEFORE USE:MOVE CYLS W/SUITABLE HAND-TRUCK. DO (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:NOT DRAG, SLIDE/ROLL CYLS. DO NOT DROP CYLS/PERMIT THEM TO STRIKE EACH OTHER. SECURE CYLS FIRMLY. LEAVE (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:VALVE PROT CAP(WHERE PROVIDED) IN-PLACE UNTIL CYL IS READY TO USE. DURING USE:USE DESIGNATED CGA FITTINGS(ING 20) RTECS #:9999999ZZ Ingred Name:ING 19:& OTHER SUPPORT EQUIP. DO NOT USE ADAPTORS. DO NOT HEAT CYL BY ANY MEANS TO INCR DISCHARGE RATE OF PROD (ING 21) RTECS #:9999999ZZ Ingred Name:ING 20:FROM CYL. DO NOT USE OILS/GREASE ON GAS-HNDLG FITTINGS/EQUIP. IMMED CONT SUPPLIER IF THERE ARE ANY (ING 22) RTECS #:9999999ZZ Ingred Name:ING 21:DFCLTIES ASSOC W/OPERATING CYL VALVE. NEVER INSERT OBJECT INTO VALVE CAP OPENINGS. DOING SO MAY DMG (ING 23) RTECS #:9999999ZZ Ingred Name:ING 22:VALVE, CAUSING LEAK. USE ADJUSTABLE STRAP WRENCH TO REMOVE OVER-TIGHT/RUSTED CAPS. NEVER STRIKE AN ARC, (ING 24) RTECS #:9999999ZZ Ingred Name:ING 23:ON COMPRESSED GAS CYL/MAKE CYL PART OF ELEC CIRCUIT. AFTER USE:CLOSE MAIN CYL VALVE. REPLACE PROT CAP. (ING 25) RTECS #:9999999ZZ Ingred Name:ING 24:MARK EMPTY CYLS "EMPTY". FOR MORE SPECIFIC HANDLING, STORAGE & OTHER INFORMATION, CONTACT NEHC . RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:MAIN HLTH HAZ ASSOC W/RELS OF THIS GAS IS ASPHY, BY DISPLACEMENT OF OXYG. HIGH CONCS CAN CAUSE OXYG-DEFICIENT ENVIRON. PERS BRTHG SUCH ATM MAY EXPER SYMPS WHICH INCL HDCHS, RINGING IN EARS, DIZZ , DROW, UNCON, NAUS, VOMIT, RESP DFCLTY, SHORTNESS OF BREATH, WHEEZING, INDIGESTION & DEPRESS OF ALL (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:SENSES. SKIN OF VICTIM OF OVEREXP MAY HAVE BLUE COLOR. UNDER SOME CIRCUMSTANCES, DEATH MAY OCCUR, DUE TO DISPLACEMENT OF OXYG. FOLLOWING EFTS ASSOC W/VARIOUS LEVELS OF OXYG ARE:12-16%:BRTHG & PULSE RATE INCR, MUSC COORD SLIGHTLY DISTURBED; 10-14%:EMOTIONAL UPSET, ABNORM FATG, DISTURBED RESP; 8-10%: (SUPP DATA) Medical Cond Aggravated by Exposure:PRE-EXISTING RESPIRATORY CONDITIONS MAY BE AGGRAVATED BY OVEREXPOSURE TO ARGON. ======================= First Aid Measures ======================= First Aid:RESCUERS SHOULD NOT ATTEMPT TO RETRIEVE VICTIMS OF EXPOS W/OUT ADEQ PPE. AT MIN, NIOSH APPRVD SCBA SHOULD BE WORN. INGEST:CALL MD IMMED . EYES:IMMED FLUSH W/POTABLE WATER FOR MIN OF 15 MINS, SEE K ASSISTANCE FROM MD . SKIN:FLUSHW/COPIOUS AMTS OF WATER. CALL MD . INHAL:REMOVE VICTIM(S) TO FRESH AIR; AS QUICKLY AS POSS. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE (ING 5) ===================== Fire Fighting Measures ===================== Extinguishing Media:NON-FLAMMABLE. USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:ARGON DOES NOT BURN; HOWEVER, CONTAINERS, WHEN INVOLVED IN FIRE, MAY RUPTURE OR BURST IN HEAT OF FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE IMMED AREA. UNCONROLLED RELS SHOULD BE RESPONDED TO BY TRAINED PERS USING PRE-PLANNED PROCS. PROPER PROT EQUIP SHOULD BE USED. IN CASE OF LEAK, CLEAR AFFECTED AREA, PROT PEOPLE & RESPOND W/TR AINED PERS. MIN PPE SHOULD BE:LEVEL NIOSH (ING 8) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:CYLS SHOULD BE STORED UPRIGHT & BE FIRMLY SECURED TO PVNT FALLING/BEING KNOCKED OVER. STORE CNTNRS AWAY FROM HEAVILY TRAFFICKED AREAS & EMER EXITS. Other Precautions:CYLS CAN BE STORE IN OPEN, BUT SHOULD BE PROT AGAINST EXTREMES OF WEATHER & FROM DAMPNESS OF GROUND TO PVNT RUSTING. CYLS SHOULD BE STORED IN DRY, WELL-VENTED AREA AWAY FROM SOURCES OF HEAT, IGNIT & D IRECT SUNLIGHT. KEEP STOR AREA (ING 11) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:MAINTAIN OXYG LEVELS >19.5% IN WORKPLACE. USE NIOSH APPRVD SUPPLIED AIR RESP PROT IF OXYG LEVELS ARE <19.5%/DURING EMER RESPONSE TO RELS OF ARGON. IF RESP PROT IS REQD, FOLLOW REQUIREMENTS OF FED OSHA REGULATORY PROT STD (29 CFR (SUPP DATA) Ventilation:USE W/ADEQ VENT. LOC EXHST VENT IS PREF, BECAUSE IT PVNTS CHEM DISPERSION INTO WORK PLACE BY ELIM IT AT ITS (SUPP DATA) Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS . Other Protective Equipment:ANSI APPRVD EYE WASH FOUNTAIN & DELUGE SHOWER . USE BODY PROT APPROP FOR TASK. SFTY SHOES ARE REC WHEN HNDLG CYLS. Work Hygienic Practices:BE AWARE OF ANY SIGNS OF DIZZ/FATG; EXPOS TO FATAL CONCS OF ARGON COULD OCCUR W/OUT ANY SIGNIFICANT WARNING (SUPP DATA) Supplemental Safety and Health RESP PROT:1910.134)/EQUIV STATE STDS. VENT:SOURCE. IF APPROP, INSTALL AUTOMATIC MONITORING EQUIP TO DETECT LEVEL OF OXYG. HYGIENE PRACT:SYMPS, DUE TO OXYG DEFICIENCY. EFTS OF OVEREXP:NAUS & VOMIT, COL LAPSE/LOSS OF CONSCIOUSNESS; <6%:CONVULSIVE MOVEMENTS, POSS RESP COLLAPSE & DEATH. CHRONIC:THERE ARE CURRENTLY NO(ING 3) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:-302F,-186C Melt/Freeze Pt:M.P/F.P Text:-309F,-189C Spec Gravity:1.38 (AIR=1) Solubility in Water:0.058 V/V @ 32F. Appearance and Odor:COLORLESS, ODORLESS GAS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. ARGON IS AN INERT GAS. Stability Condition to Avoid:AVOID EXPOSING CYLINDERS TO EXTREMELY HIGH TEMPERATURES, WHICH COULD CAUSE CYLINDERS TO RUPTURE OR BURST. Hazardous Decomposition Products:NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE DISPOSAL MUST BE I/A/W APPROPRIATE FEDERAL, STATE & LOCAL REGULATIONS. RETURN CYLINDERS W/ANY RESIDUAL PRODUCT TO MFR. DO NOT DISPOSE OF LOCALLY. FOR EMERGENCY DISP, SECURE CYLINDER & SLOWLY DIS CHARGE GAS TO ATM IN WELL-VENTED AREA/OUTDOORS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.