NALFLEET LIMITED (NALFLOC LTD) -- NALCOOL 2000 -- 6850-01-085-4719
===================== Product Identification ===================== Product ID:NALCOOL 2000 MSDS Date:12/03/1997 FSC:6850 NIIN:01-085-4719 Status Code:A === Responsible Party === Company Name:NALFLEET LIMITED (NALFLOC LTD) Address:WINNINGTON AVE Box:11 City:NORTHWICH, CHESHIRE, CW8 4DX Country:UK Info Phone Num:01606-74488 Emergency Phone Num:(INTL)+44(0) 1865 407333 CAGE:TO043 === Contractor Identification === Company Name:NALFLEET INC Address:195 MOUNTAIN AVE Box:City:SPRINGFIELD State:NJ ZIP:07081-1755 Country:US Phone:973-379 -1340 Contract Num:SP0450-99-M-C830 CAGE:95719 Company Name:NALFLEET INC Address:195 MOUNTAIN AVE Box:City:SPRINGFIELD State:NJ ZIP:07081-1755 Country:US Phone:973-379 -1340 Contract Num:SP0450-99-M-C831 CAGE:95719 Company Name:NALFLEET INC Address:195 MOUNTAIN AVE Box:City:SPRINGFIELD State:NJ ZIP:07081-1755 Country:US Phone:973-379 -1340 Contract Num:SPO450-00-M-D179 CAGE:95719 Company Name:NALFLEET LIMITED Address:WINNINGTON AVE Box:11 City:NORTHWICH, CHESHIRE, CW8 4DX Country:UK Phone:01606-74488/01144(0)1865407333 CAGE:TO043 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM NITRITE CAS:7632-00-0 RTECS #:RA1225000 Minumum % Wt:4. Maxumum % Wt:6. Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) > 2,000 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS: EYES, SKIN, RESPIRATORY AND GASTRINTESTINAL TRACTS (HMIS). ACUTE - INHALE: MAY CAUSE IRRITATION OF MUCOUS MEMBRANES. EYE/SKIN: CAN CAUSE MODERATE IRRITATION. INGESTION: HARMFUL IF SWALL OWED. MAY CAUSE GASTROINTESTINAL TRACT IRRITATION. COMPONENTS OF PRODUCT CREATE FORMATION OF METHEMOGLOBIN. PREGNANT WOMEN ARE PARTICULARLY SENSITIVE TO METHEMOGLOBINEMIA. MAY CAUSE A DECREASE IN BLO OD PRESSURE AND CYANOSIS. CHRONIC - REPEATED INGESTION OF SMALL AMOUNTS OF SODIUM NITRITE CAUSES DROPS IN BLOOD PRESSURE, RAPID PULSE, HEADACHES AND VISUAL DISTURBANCES. IT MAY REACT WITH AMINES IN BO DY TO FORM CARCINOGENIC NITROSAMINES. Explanation of Carcinogenicity:IT MAY REACT WITH AMINES IN THE BODY TO FORM CARCINOGENIC NITROSAMINES. Effects of Overexposure:MODERATE IRRITATION, DROPS IN BLOOD PRESSURE, RAPID PULSE, HEADACHES AND VISUAL DISTURBANCES ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYE CONTACT: IMMEDIATELY GENTLY FLUSH WITH CLEAN WATER FOR AT LEAST 15 MINUTES. HOLD EYELIDS OPEN. OBTAIN MEDICAL ATTENTION IMMEDIATELY. SKIN CONTACT: REMOV E CONTAMINATED CLOTHING. WASH OFF AFFECTED AREA IMMEDIATELY WITH PLENTY OF WATER. INHALATION: USUALLY NOT NECESSARY UNLESS AEROSOL/MISTS ARE GENERATED. REMOVE TO FRESH AIR. IF NECESSARY GIVE ARTIFICI AL RESPIRATION . OBTAIN MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE. IF CONSCIOUS, WASH OUT MOUTH AND GIVE ONE PINT OF WATER TO DRINK. OBTAIN MEDICAL ATTENTION IMMEDIAT ELY. ===================== Fire Fighting Measures ===================== Flash Point:NOT FLAMMABLE Autoignition Temp:Autoignition Temp Text:NA Extinguishing Media:NOT EXPECTED TO BURN. USE EXTINGUISHING MEDIA APPOPRIATE FOR SURROUNDING FIRE Fire Fighting Procedures:IN CASE OF FIRE, WEAR A FULL FACE POSTIVE -PRESSURE SELF CONTAINED BREATHING APPPARATUS AND PROTECTIVE SUIT. Unusual Fire/Explosion Hazard:MAY EVOLVE TOXIC GASES OR FUMES UNDER FIRE CONDITIONS, OXIDES OF NITROGEN. IF PRODUCT IS ALLOWED TO DRY, THE SODIUM NITRITE IS AN OXIDIZING AGENT AND CAN INITIATE THE COMBUSTION OF OTHER MATERIALS. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR CHEMICAL RESISTANT APRON, CHEMICAL SPLASH GOGGLES, IMPERVIOUS GLOVES AND WELLINGTON BOOTS. DO NOT ALLOW TO ENTER SEWERS OR WATER COURSES. IF IT DOES, INFORM AUTHORITIES. CONTAIN AND ABSORB WITH S AND OR VERMICULITE AND MIX WELL. COLLECTUP AND REMOVE TO A SAFE PLACE UNTIL DISPOSAL. DO NOT USE COTTON WASTE, SAWDUST OR OTHER COMBUSTIBLE SUBSTANCES AS ABSORBENTS, THESE MAY IGNITE WHEN DRIED OUT. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, WELL VENTILATED AREA AWAY FROM INCOMPATIBLES. STORAGE FOR MORE THAN TWO YEARS IS NOT RECOMMENDED. EQUIPMENT FOR STORAGE SHOULD BE CONSTRUCTED FROM STAINLESS STEEL, PVC, BUTYL/NITRILE RUBBER. AVOID USE OF ALUMINUM, COPPER, ZINC AND THEIR ALLOYS, BRASS AND GALVANIZED METALS. Other Precautions:AVOID BREATHING VAPORS OR MISTS. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR DRINKING. REMOVE CONTAMINATED CLOTHING PROMPTLY. LAUNDER BEFORE REUSE. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY NEEDED. IF EXCESSIVE MISTING IS EXPECTED, WEAR NIOSH-APPROVED VAPOR AND MIST RESPIRATOR (REFER TO 29 CFR 1910.134) Ventilation:USE A CLOSED DESIGN SYSTEM. LOCAL EXHAUST VENTILATION IS RECOMMENDED WHERE SIGNIFICANT AEROSOLS/MISTS ARE GENERATED. Protective Gloves:NITRILE, NEOPRENE, PVC Eye Protection:CHEMICAL SPLASH GOGGLES Other Protective Equipment:EYE BATH, WASHING FACILITY, LAB COAT OR UNIFORM. Work Hygienic Practices:GOOD PRACTICE REQUIRES THAT GROSS AMOUNT OF ANY CHEMICAL BE REMOVED FROM THE SKIN AS SOON AS PRACTICAL. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:B3 Boiling Pt:B.P. Text:N/E Melt/Freeze Pt:M.P/F.P Text:NE Vapor Pres:SAME AS WATER Spec Gravity:1.095- 1.125 pH:11.3-11.8 Viscosity:NE Solubility in Water:COMPLETE Appearance and Odor:DARK RED LIQUID,SLIGHT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, REDUCING AGENTS, ORGANIC MATERIALS Stability Condition to Avoid:STABLE UNDER AMBIENT CONDITIONS. Hazardous Decomposition Products:MAY EVOLVE TOXIC GASES OR FUMES, OXIDES OF NITROGEN. =================== Toxicological Information =================== Toxicological Information:PRIMARY SKIN IRRITATION: 0.5/8.0; PRIMARY EYE IRRITATION: 16.7/110.0 ===================== Ecological Information ===================== Ecological:NITRITE IS TOXIC TO FISH. CHEMICAL OXYGEN DEMAND (COD) = 67000 MG/L. ECOTOXICOLOGICAL EFFECTS: LC50/96H/LEPOMIS MACROCHIRUS (BLUEGILL SUNFISH) = > 1000 MG/L; LC50/96H/ONCORHYNCHUS MYKISS (RAINBOW TRO UT) = 200 MG/L. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL LAWS AND REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.