GLIDDEN COMPANY -- 3700 SPRED ENAMEL LATEX SEMI-GLOSS-PURE WHITE -- 8010-00F036999
===================== Product Identification ===================== Product ID:3700 SPRED ENAMEL LATEX SEMI-GLOSS-PURE WHITE MSDS Date:02/23/1994 FSC:8010 NIIN:00F036999 === Responsible Party === Company Name:GLIDDEN COMPANY Address:925 EUCLID AVENUE City:CLEVELAND State:OH ZIP:44115 Country:US Info Phone Num:216-344-8000/800-545-2643 Emergency Phone Num:800-545-2643/216-826-5566 CAGE:01PD6 === Contractor Identification === Company Name:GLIDDEN PAINT, ICI PAINTS NORTH AMERICA Address:925 EUCLID AVE Box:City:CLEVELAND State:OH ZIP:44115 Country:US Phone:800-545-2643/216-344-8207 CAGE:01PD6 ============= Composition/Information on Ingredients ============= Ingred Name:TITANIUM DIOXIDE, TIO2 (SUSPECTED ANIMAL CARCINOGEN BY IARC-GROUP 3) *94-3* CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 10-20% OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM (DUST) Ingred Name:STYRENE ACRYLIC COPOLYMER Fraction by Wt: 1-5% Ingred Name:VINYL ACRYLIC RESIN *93-1* CAS:25067-01-0 Fraction by Wt: 10-20% Ingred Name:METHACRYLIC ACID METHYL ESTER, POLYMER W/BUTYL ACRYLATE & STYRENE *93-4* CAS:27136-15-8 Fraction by Wt: 1-5% Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 40-50% Ingred Name:1,2-PROPANEDIOL (PROPYLENE GLYCOL) CAS:57-55-6 RTECS #:TY2000000 Fraction by Wt: 5-10% Ingred Name:CLAY (KAOLIN), ALUMINUM SILICATE CAS:1332-58-7 RTECS #:GF1670500 Fraction by Wt: 5-10% ACGIH TLV:10 MG/CUM TOTAL DUST Ingred Name:SILICON DIOXIDE, CELITE 322 CAS:7631-86-9 RTECS #:VV3100000 Fraction by Wt: 1-5% OSHA PEL:80 MG/CUM ACGIH TLV:0.2 MG/CUM Ingred Name:VINYL ACETATE CAS:108-05-4 RTECS #:AK0875000 Fraction by Wt: 1-1.0% Other REC Limits:10 PPM OSHA PEL:20 PPM ACGIH TLV:20 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): 5 GM/KG PROPYLENE GLYCOL Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALATION: IRRITATION OF RESPIRATORY TRACT/ANESTHETIC. SKIN: IRRITATION. PROLONGED/REPEATED CONTACT CAN CAUSE DERMATITIS/SEVERE IRRITATION/POSSIBLE SENSITIZATION. EYES: IRRITATION, PROLONGED/REPEATED CONTACT: SEVERE IRRITATION. INGESTION:CNS DEPRESSION/ANESTHETIC EFFECTS/KIDNEY DAMAGE. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, DROWSINESS, DIZZINESS, LIGHTHEADEDNESS, UNCOORDINATION, COUGHING, NARCOSIS, LOSS OF CONSCIOUSNESS, BLISTERING, TEARING, REDNESS, HEADACHE, NAUSEA, VOMITING, DIARRHEA, GI DISTURBANCES. Medical Cond Aggravated by Exposure:EYE, SKIN, RESPIRATORY DISORDERS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE & SUPPORT BREATHING. HAVE TRAINED PERSON GIVE OXYGEN IF NECESSARY. SKIN: FLUSH W/WATER. WASH THOROUGHLY W/SOAP & WATER. EYES: FLUSH IMMEDIATELY W/PLENTY WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:NONE Upper Limits:13.4 Extinguishing Media:DRY CHEMICAL/FOAM, WATER FOG, CO2 Fire Fighting Procedures:WATER MAY BE USED TO COOL & PROTECT EXPOSED CONTAINERS. USE FULL PROTECTIVE CLOTHING, EYE PROTECTION & SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY BURST/EXPLODE WHEN EXPOSED TO EXTREME HEAT/FIRE. VAPORS ARE >AIR & MAY TRAVEL LONG DISTANCES TO AN IGNITION SOURCE & FLASH BACK. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. VENTILATE AREA. EVACUATE PERSONNEL. PLACE COLLECTED MATERIAL IN PROPER CONTAINER. TOXIC TO FISH. USE PROTECTIVE EQUIPMENT. LARGE: SHUT OFF LEAK SAFELY. DIKE & CONTAIN. PUMP TO STORAGE/SALVAGE VESSELS. (SEE SUPP) ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY CLOSED & UPRIGHT WHEN NOT IN USE. STORE < 100F. KEEP AWAY FROM HEAT, SPARKS & OPEN FLAME. KEEP FROM FREEZING. Other Precautions:USE W/ADEQUATE VENTILATION. DON'T TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. AVOID CONTACT W/SKIN/EYES & BREATHING OF VAPORS. AVOID CONDITIONS WHICH RESULT IN FORMAION OF INHALABLE PARTICLES. GRO UND EQUIPMENT WHEN TRANSFERRING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE A NIOSH/MSHA APPROVED RESPIRATOR BY OSHA STANDARD 29 CFR 1910.134. Ventilation:DILUTION VENTILATION/LOCAL EXHAUST TO PREVENT BUILD-UP OF VAPORS. Protective Gloves:IMPERVIOUS Eye Protection:SAFETY GLASSES/GOGGLES. Other Protective Equipment:EYE WASH, SAFETY SHOWER, IMPERVIOUS CLOTHING, APRON. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH HANDS THOROUGHLY AFTER HANDLING, BEFORE EATING/SMOKING. Supplemental Safety and Health INCOMPATIBILITY CONT'D: CAUSTICS, MINERAL ACIDS, SODIUM, POTASSIUM, ULTRAVIOLET LIGHT. SPILL PROC CONT'D: LARGE: USE ABSORBENT TO PICK UP EXCESS RESIDUE. KEEP SALVAGABLE MATERIAL & RINSE WATER OUT OF SEWERS & WATER COURSES. SMALL: USE ABSORBENT TO PICK UP RESIDUE & DISPOSE OF PROPERLY. AVOID DISCHARGE TO NATURAL WATERS ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:163-212F Spec Gravity:1.21 Appearance and Odor:WHITE LIQUID Percent Volatiles by Volume:65.08 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS/ACIDS/REDUCING AGENTS/BASES/ALUMINUM/ZINC/METALS/PEROXIDES/NITRIC ACID/HYDROFLUORIC ACID/MAGNESIUM. (SEE SUPP) Stability Condition to Avoid:SUNLIGHT, ELEVATED TEMPS, FREEZING, SPARKS, HEAT, OPEN FLAME. Hazardous Decomposition Products:CO, CO2, ACRID FUMES, OXYGEN, ALDEHYDES, TOXIC GASES, ACIDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.