FIRST BRANDS CORP -- PRESTONE GIANT SPRAY DE-ICER, AS244 -- 6850-00N056399 
=====================  Product Identification  =====================

Product ID:PRESTONE GIANT SPRAY DE-ICER, AS244
MSDS Date:01/24/1991
FSC:6850
NIIN:00N056399
=== Responsible Party ===
Company Name:FIRST BRANDS CORP
Address:83 WOOSTER HTS RD BLDG 301
City:DANBURY
State:CT
ZIP:06813-1911
Country:US
Info Phone Num:203-731-2300
Emergency Phone Num:800-424-9300 (CHEMTREC)
CAGE:DO273
=== Contractor Identification ===
Company Name:FIRST BRANDS CORP (PHONE:203-728-6194)
Address:88 LONG HILL ST
City:EAST HARTFORD
State:CT
ZIP:06108
Phone:203-731-2300, CHEMTREC 800-424-9300
CAGE:DO273
Company Name:PRESTONE PRODUCTS CORP
Address:39 OLD RIDGEBURY RD
Box:City:DANBURY
State:CT
ZIP:06810-5109
Country:US
Phone:203-731-3686/830-7865
CAGE:0CXZ7

=============  Composition/Information on Ingredients  =============

Ingred Name:ETHYLENE GLYCOL (SARA 313) (CERCLA)
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: 5-9%
OSHA PEL:N/K 
ACGIH TLV:C 50 PPM, VAPOR
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB

Ingred Name:METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 70-80%
OSHA PEL:S, 200 PPM
ACGIH TLV:S, 200 PPM/250 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Ingred Name:1,2-PROPANEDIOL; (PROPYLENE GLYCOL)
CAS:57-55-6
RTECS #:TY2000000
Fraction by Wt: 5-9%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:CARBON DIOXIDE
CAS:124-38-9
RTECS #:FF6400000
Fraction by Wt: 1-5%
OSHA PEL:5000 PPM
ACGIH TLV:5000 PPM/30000 STEL

Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 5-9%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:SUPDAT:FOLLOWS SWALLOWING OF LG VOLUMES OF ETHYLENE GLYCOL.
    CARD FAILURE & PULM EDEMA MAY DEVELOP. SKIN ABSORP: (ING 7)
RTECS #:9999999ZZ

Ingred Name:ING 6:PRLNGD & WIDESPREAD CONT MAY RSLT IN ABSORP OF
    HARMFUL AMTS OF METHANOL. INHAL:METHANOL MAY CAUSE DIZZ, (ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7:DROW, DISTURB OF VISION, & TINGLING, NUMBNESS &
    SHOOTING PAINS IN HANDS & FOREARMS. ETHYLENE GLYCOL MAY (ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8:CAUSE IRRIT OF NOSE & THROAT W/HDCH, PARTICULARLY
    FROM MISTS. HIGH VAP CONCS MAY PRDCE NAUS, VOMIT, HDCH, (ING 10)
RTECS #:9999999ZZ

Ingred Name:ING 9:DIZZ & IRREGULAR EYE MOVEMENTS. SKIN:PRLNGD CONT TO
    METHANOL MAY CAUSE REDDENING & DEFAT. EYE:MAY CAUSE (ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 10:DISCOMFORT W/MILD REDNESS & SWELL OF CONJ & POSS
    TEMPORARY SUPERFICIAL INJURY OF CORNEA. CHRONIC:LONG (ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11:TERM RPTD OVEREXP TO METHANOL VAP CONCS OF 3000
    PPM/GREATER MAY ALLOW CUMULATIVE EFT TO OCCUR W/RESULTING(ING 13)
RTECS #:9999999ZZ

Ingred Name:ING 12:NAUS, VOMIT, HDCH, RINGING IN EARS, INSOMNIA,
    TREMBLING, UNSTEADY GAIT, VERTIGO, CLOUDED & DOUBLE VISION.(ING 14)
RTECS #:9999999ZZ

Ingred Name:ING 13:LIVER &/OR KIDNEY INJURY MAY OCCUR. PRLNGD OVEREXP @
    LEVELS OF 800-1000 PPM MAY RSLT IN SEV EYE DMG IN (ING 15)
RTECS #:9999999ZZ

Ingred Name:ING 14:SOME PEOPLE. RPTD SKIN CONT MAY CAUSE SENSIT
    W/ALLERGIC CONT DERM. ANIMAL STUDIES SUGGEST THAT ETHYLENE (ING 16)
RTECS #:9999999ZZ

Ingred Name:ING 15:GLYCOL @ HIGH DOSES IS TO BE REGARDED AS ANIMAL
    TERATOGEN. FOR MORE INFORMATION, CONTACT NECH .
RTECS #:9999999ZZ

Ingred Name:FIRST AID PROC:EMER MED FACILITY. TAKE PATIENT & CNTNR TO
    NEAREST EMER MED FACILITY. SKIN:REMOVE CONTAMD CLTHG.(ING 18)
RTECS #:9999999ZZ

Ingred Name:ING 17:IMMED WASH EXPOS AREAS W/SOAP & COPIOUS AMTS OF
    WATER. IF IRRIT/REDNESS DEVELOPS & PERSISTS, SEEK MED (ING 19)
RTECS #:9999999ZZ

Ingred Name:ING 18:ATTN. EYES:FLUSH W/COPIOUS AMTS OF CLEAN WATER,
    USING STEADY STREAM FOR MIN OF 15 MINS. IF IRRIT, PAIN, (ING 20)
RTECS #:9999999ZZ

Ingred Name:ING 19:SWELL/TEARING PERSIST, SEEK MED ATTN. FOR MORE INFO
    CONCERNING NOTES TO MD, CONTACT NEHC .
RTECS #:9999999ZZ

Ingred Name:VENT:EXHAUST MAY BE NEEDED TO MAINTAIN EXPOSURE LEVELS
    BELOW APPLICABLE LIMITS.
RTECS #:9999999ZZ

Ingred Name:RESP PROT:29 CFR 1910.134 & GOOD INDUSTRIAL HYGIENE
    PRACTICE.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INGEST:CONTAINS METHANOL &
    ETHYLENE GLYCOL. METHANOL MAY CAUSE NAUS, ABDOM PAIN, VOMIT,
    SHORTNESS OF BREATH, FATG & LEG CRAMPS. NERV SYS EFTS INCL:HDCH,
    CONFUSN, DRUNKEN BEHAVIOR, CNS DEPRESS, C OMA & DEATH. VISUAL EFTS
    FROM METHANOL INCL BLURRED VISION, DOUBLE VISION, CHANGES IN COLOR
    PERCEPTION,(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:RESTRICTION OF VISUAL FIELDS &
    COMPLETE BLNDNESS. W/MASSIVE OVERDOSES, LIVER, KIDNEY & HEART
    MUSCLE INJURY HAVE BEEN DESCRIBED. THERE MAY BE DELAY OF SEVERAL
    HRS BETWEEN SWALLOWING METHANOL &  ONSET OF SIGNS & SYMPS. INGEST
    OF MOD QTYS OF METHANOL ALSO PRDCES METABOLIC ACIDOSIS. ONSET OF
    SYMPS MAY BE (SUPDAT)
Medical Cond Aggravated by Exposure:DUE TO ITS DEFAT PROPERTIES,
    METHANOL MAY AGGRAVATE EXISTING SKIN CNDTN, E.G., ECZEMA. DUE TO
    ITS LIVER & KIDNEY INJURING POTNTL, PROD MAY EXACERBATE EXISTING
    LIVER AND/OR KIDNEY DISEASES.

=======================  First Aid Measures  =======================

First Aid:INGEST:GIVE 2 GLASSES OF WATER & INDUCE VOMIT IMMED. NEVER
    GIVE ANYTHING BY MOUTH TO UNCON PERSON. GET MED HELP URGENTLY BY
    CALLING PHYS, EMER ROOM/POIS CTL CTR. ETHANOL (WHISKEY, BRANDY,
    ETC.) IS EFT IVE ANTIDOTE. MED PERS MAY INSTRUCT YOUTO ADMIN
    ETHANOL TO PATIENT DEPENDING ON NUMBER OF VARIABLES SUCH AS AMT OF
    PROD SWALLOWED, TIME ELAPSED SINCE INGEST & TIME NEEDED TO GET
    PATIENT TO (ING 17)

=====================  Fire Fighting Measures  =====================

Flash Point Method:PMCC
Flash Point:58F,14C
Extinguishing Media:FOAM, ALCOHOL FOAM, CARBON DIOXIDE OR DRY CHEMICAL
    FOR SMALL FIRE. WATER FOG FOR LARGE FIRE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
    EQUIPMENT . AEROSOL FLAME EXTENTION:>18 IN. LEVEL 2 AEROSOL.
Unusual Fire/Explosion Hazard:DO NOT INCINERATE AEROSOL CONTAINER/STORE
    CONTAINER IN AREA >120F(49C). CANS OF PACKAGED PRODUCT MAY RUPTURE
    IF EXPOSED TO HEAT.

==================  Accidental Release Measures  ==================

Spill Release Procedures:WEAR APPROP PERSONAL PROTECTIVE EQUIPMENT &
    REMOVE ALL SOURCES OF IGNITION. COLLECT MATERIAL FOR DISPOSAL IN
    CONTAINER SUITABLE FOR FLAMMABLE WASTE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:DANGER:FLAMM. MAY BE FATAL/CAUSE
    BLNDNESS IF SWALLOWED. DO NOT SWALLOW. DO NOT BREATHE VAP. USE ONLY
    W/ADEQ VENT. AVOID CONT W/EYES, SKIN & CLOTHING.
Other Precautions:KEEP AWAY FROM SOURCES OF HEAT, SPARKS, FLAME & OUT
    OF DIRECT SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES >120F. OBSERVE
    ALL REQUIREMENTS OF PLANT, COMPANY/GOVT REGS. KEEP OUT OF REACH OF
    CHILDREN.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:OPERATIONS WHERE TLV MAY BE EXCEEDED, NIOSH
    APPRVD SUPPLIED AIR RESP IS REC. ODOR IS NOT RELIABLE INDICATOR OF
    OVEREXP, SO NIOSH APPRVD AIR-PURIFYING EQUIP IS NOT REC. EQUIP
    SELECTION DEPENDS ON CONTA M TYPE & CONC, SELECT I/A/W (ING 22)
Ventilation:GEN VENT SHOULD BE ADEQ FOR NORM USE. FOR OPERATIONS WHERE
    TLV MAY BE EXCEEDED, FORCED VENT SUCH AS LOCAL (ING 21)
Protective Gloves:CHEM RESIST, SUCH AS NITRILE/BUTYL RUBB.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . PROT
    CLTHG IF NEEDED TO AVOID PRLNGD/RPTD SKIN CONTACT.
Work Hygienic Practices:CONTAMD CLTHG SHOULD BE REMOVED & LAUNDERED
    BEFORE RE-USE. WASH EXPOSED SKIN W/SOAP AND WATER.
Supplemental Safety and Health
FL PT:58.0F,14.4C. METH:PMCC. EFTS OF OVEREXP:DELAYED UP TO 48HRS.
    60-200 ML IS FATAL DOSE FOR MOST ADULTS. INGEST OF AS LITTLE AS 10
    ML MAY CAUSE BLNDNESS. ETHYLENE GLYCOL, IN ADDN TO SHARING MANY OF 
    GI & NERV SYS EFTS OF METHANOL, ALSO CAUSES METABOLIC ACIDOSIS. IN
    ADDN, SEV KIDNEY DMG & POSS KIDNEY FAILURE (ING 6)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:158F,70C
Melt/Freeze Pt:M.P/F.P Text:>-100F,>-73
Vapor Pres:47 @ 68F
Vapor Density:>1
Spec Gravity:0.857 
Evaporation Rate & Reference:6 (BUTYL ACETATE =1)
Solubility in Water:100% BY WGT
Appearance and Odor:CLEAR COLORLESS LIQUID, ALCOHOL ODOR.
Percent Volatiles by Volume:100

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
NORMALLY NONE.
Stability Condition to Avoid:HEAT, SPARKS AND OPEN FLAMES.
Hazardous Decomposition Products:BURNING MAY PRODUCE CO OR CO*2.

====================  Disposal Considerations  ====================

Waste Disposal Methods:WASTE MATERIAL IS RCRA HAZARDOUS WASTE DUE TO
    IGNITABILITY. INCINERATION OR LANDFILLING SHOULD BE CARRIED OUT
    I/A/W APPLICABLE RCRA FEDERAL, STATE AND LOCAL REGULATIONS.

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