J.T.BAKER INC. -- SODIUM NITRITE -- 6810-00-241-1140
===================== Product Identification ===================== Product ID:SODIUM NITRITE MSDS Date:04/14/1988 FSC:6810 NIIN:00-241-1140 === Responsible Party === Company Name:J.T.BAKER INC. Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865 Info Phone Num:201-859-2151 Emergency Phone Num:201-859-2151 OR 800-424-9300CHEMTRE CAGE:HO852 === Contractor Identification === Company Name:J.T.BAKER INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08885 Phone:201-859-2151 CAGE:HO852 Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM NITRITE (SARA III) CAS:7632-00-0 RTECS #:RA1225000 Fraction by Wt: >97% EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 ORAL RAT=85MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:SEE SIGNS & SYMPTOMS OF OVEREXPOSURE. Explanation of Carcinogenicity:NITROSAMINE FORMATION MAY OCCUR WHEN SODIUM NITRITE CONTACTS SECONDARY/TERTIARY AMINES.NITROSAMINES ARE POT. CARCINOGENS Effects of Overexposure:EYES/SKIN:IRRITATION;INHALATION:IRRITATION TO UPPER RESPIRATORY TRACT;INGESTION:IRRITATION & BURNING TO MOUTH & STOMACH.INGESTION OF LARGE QUANTITIES MAY CAUSE NAUSEA,VOMITING,CYANOSIS,CONVULSIONS & C OMA. Medical Cond Aggravated by Exposure:NONE IDENTIFIED. ======================= First Aid Measures ======================= First Aid:EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER;SKIN:FLUSH WITH WATER;INHALATION:REMOVE TO FRESH AIR.GIVE OXYGEN/CPR IF NEEDED;INGESTION:IF CONSCIOUS,GIVE LARGE AMOUNTS OF WATER.INDUCE VOMIT. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY Fire Fighting Procedures:WEAR SCBA & PROTECTIVE EQUIPMENT.MOVE CONTAINERS FROM FIRE AREA IF POSSIBLE.USE WATER SPRAY TO KEEP FIRE EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard:STRONG OXIDIZER.CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE.CAN REACT VIOLENTLY WITH SHOCK,FRICTION OR HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP DRY SPILLS.SM SPILLS:FLUSH AWAY WITH WATER.AVOID CONTAIMINATING SEWERS,STREAMS,PONDS,ETC.AVOID COMBUSTIBLES,THEY CAN BE SERIOUS FIRE HAZARD. LG SPILL:DIKE FOR LATER DISPOSAL. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY PLACE AWAY FROM COMBUST,ACIDS,REDUCERS.STORE IN NON-COMBUST BUILDING.MIX WITH INCOMPATIBLES MAY CAUSE EXPLOSION. Other Precautions:SODIUM NITRITE SHOULD NOT BE MIXED WITH OTHER CHEMICALS UNLESS THE REACTION IS KNOWN IN ADVANCE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DUST/MIST RESPIR,RECOMMENDED FOR SODIUM NITRITE DUST (NIOSH APPRD) Ventilation:LOCAL EXHAUST TO ELIMINATE MISTS/FUMES/GASES,DUSTS. Protective Gloves:RUBBER Eye Protection:GOGGLES/FACE SHIELD Other Protective Equipment:RUBBER SHOES,RUBBER APRON,OTHER PROTECTIVE CLOTHING. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health MATERIAL IS HYGROSCOPIC. ================== Physical/Chemical Properties ================== HCC:D1 Boiling Pt:B.P. Text:608F(320C) Melt/Freeze Pt:M.P/F.P Text:520F(271C) Vapor Density:2.4 Spec Gravity:2.17 Evaporation Rate & Reference:N/A(SOLID) Solubility in Water:APPRECIABLE Appearance and Odor:WHITE TO YELLOW GRANULES OR POWDER.ODORLESS. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CYANIDES,STRONG ACIDS,STRONG REDUCERS,COMBUSTIBLE MATERIAL,ORGANIC MATERIALS,AMMONIUM SALTS. Stability Condition to Avoid:SHOCK,FRICTION,HEAT,FLAME,MOISTURE Hazardous Decomposition Products:NITROGEN OXIDES AND OTHER OXIDES; TOXIC FUMES; FLAM GAS ==================== Disposal Considerations ==================== Waste Disposal Methods:ELIMINATE IGN. SOURCES. CONTACT QUALIFIED SUPPLIER FOR DISPOS METHODS, OR SORT, CLASSIFY & PUT IN A BOX PROPERLY LABELED. SALVAGE FOR REUSE OR DISPOSE OF AS SCRAP. PACKAGE & DISPOSE ACCORDANCE W/LOCA L, & FED REGS/ TRANSPORT TO REFINERY FOR RECYCLING Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.