BARIUM & CHEMICALS INC -- BARIUM CHROMATE -- 6850-00N012831
===================== Product Identification ===================== Product ID:BARIUM CHROMATE MSDS Date:08/15/1990 FSC:6850 NIIN:00N012831 === Responsible Party === Company Name:BARIUM & CHEMICALS INC Address:BOX 218 COUNTY ROAD 44 City:STEUBENVILLE State:OH ZIP:43952 Country:US Info Phone Num:614-282-9776 Emergency Phone Num:614-282-7197;614-282-9776 CAGE:DO062 === Contractor Identification === Company Name:BARIUM & CHEMICAL Address:COUNTY RD 44 Box:218 City:STEUBENVILLE Phone:614-282-9776 CAGE:DO062 Company Name:BARIUM AND CHEMICALS INC Address:COUNTY RD 44 Box:218 City:STEUBENVILLE State:OH ZIP:43952 Country:US Phone:740-282-9776 CAGE:20865 ============= Composition/Information on Ingredients ============= Ingred Name:BARIUM CHROMATE (VI) CONTAINING 54.2% ELEMENTAL BARIUM & 39.5% ELEMENTAL CHROMIUM. PEL/TLV AS CHROMATES: 0.1 (ING 2) CAS:10294-40-3 RTECS #:CQ8760000 OSHA PEL:0.5 MG/M3 (BA) ACGIH TLV:0.5 MG/M3 (BA) Ingred Name:ING 1: MG/M3 PEL; 0.05 MG/M3 TLV; 0.001 MG/M3 C. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:WORKERS MAY EXPERIENCE AN INCREASED INCIDENCE OF LUNG CANCER. POISONING MAY AFFECT THE BLOOD, CNS, LIVER AND KIDNEYS. BARIUM COMPOUNDS ARE SKIN, EYE AND MUCOUS MEMBRANE IRRITANTS. Explanation of Carcinogenicity:BARIUM CHROMATE (VI):IARC MONOGRAPHS, SUPPLEMENT, VOL 49, PG 49, 1990: GROUP 1. NTP 7TH ANNUAL REPORT ON (SUPP DATA) Effects of Overexposure:VOMITING, VIOLENT DIARRHEA, ABDOMINAL PAIN, DIFFICULTY IN BREATHING, SLOW PULSE AND IRREGULAR HEARTBEAT. MAY CAUSE BLEEDING AND ULCERATION OF NASAL SEPTUM. SORE THROAT, COUGHING AND POSSIBLE LIVER DAM AGE. SKIN RASHES, LARGE DOSES MAY CAUSECARDIAC AND RESPIRATORY FAILURE AND HEMORRHAGES IN THE GI TRACT AND KIDNEYS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE FROM EXPOSURE AREA. SKIN: REMOVE CONTAMINATED CLOTHING AND SHOES. WASH AFFECTED AREA WITH SOAP AND WATER. EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MIN. GET MEDICAL ATTENTI ON. INGEST: MEDICAL PERSONNEL SHOULD REMOVE CHROMATES BY GASTRIC LAVAGE. ===================== Fire Fighting Measures ===================== Lower Limits:NON-FLAMM Upper Limits:NON-FLAMM Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE OR WATER SPRAY. FOR LARGE FIRES - FOG. Fire Fighting Procedures:IN STORAGE AREA - USE UNMANNED HOSE HOLDER AND WITHDRAW FROM AREA UNTIL FIRE IS OUT. WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . ================== Accidental Release Measures ================== Spill Release Procedures:KEEP COMBUSTIBLES AWAY FROM SPILLED MATERIAL. SHOVEL MATERIAL INTO CLEAN DRY CONTAINER AND COVER. MOVE CONTAINERS FROM SPILL AREA. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM COMBUSTIBLES. STORE IN DRY AREA. KEEP CONTAINERS CLOSED. Other Precautions:KEEP AWAY FROM REDUCING AGENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED HIGH EFFICIENCY PARTICULATE RESPIRATOR WITH FULL FACE PIECE. Ventilation:LOCAL EXHAUST: SUFFICIENT TO ELIMINATE DUSTS. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKER GOGGLES . Other Protective Equipment:IMPERVIOUS CLOTHING AND EQUIPMENT TO PREVENT ANY POSSIBILITY OF SKIN CONTACT WITH SUBSTANCE. Work Hygienic Practices:WASH CLOTHING BEFORE REUSE. WORKERS SHOULD TAKE HOT SHOWERS AFTER WORK IS FINISHED. Supplemental Safety and Health CARCIN: CARCINOGENS, 1992: KNOWN TO BE CARCINOGENIC. ================== Physical/Chemical Properties ================== HCC:T2 Boiling Pt:B.P. Text:DECOMPOSES Melt/Freeze Pt:M.P/F.P Text:DECOMPOSES Vapor Pres:NEGLIGIBLE Spec Gravity:4.5 (H*2O=1) Solubility in Water:INSOLUBLE Appearance and Odor:YELLOW POWDER - NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REDUCING AGENTS MAY REACT VIGOROUSLY. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTAMINATED RESIDUE AND SWEEPINGS ARE CONSIDERED A TOXIC WASTE. MUST BE DISPOSED OF IN A LICENSED TOXIC WASTE DUMP. DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS . 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