ANACHEMIA CHEMICALS INC -- HYDROCHLORIC ACID 5-<10% -- 6810-00N069193
===================== Product Identification ===================== Product ID:HYDROCHLORIC ACID 5-<10% MSDS Date:03/09/1994 FSC:6810 NIIN:00N069193 === Responsible Party === Company Name:ANACHEMIA CHEMICALS INC Address:3 LINCOLN BLVD City:ROUSES POINT State:NY ZIP:12079 Country:US Info Phone Num:518-297-4444 Emergency Phone Num:518-297-4444;800-424-9300(CHEMTREC) CAGE:4A444 === Contractor Identification === Company Name:ANACHEMIA CHEMICALS INC Box:UNKNOW CAGE:3A444 Company Name:ANACHEMIA CHEMICALS INC Address:3 LINCOLN BLVD Box:City:ROUSES POINT State:NY ZIP:12979 Country:US Phone:518-297-4444 CAGE:4A444 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROCHLORIC ACID (SARA 302/313) (CERCLA) CAS:7647-01-0 RTECS #:MW4025000 Fraction by Wt: 5-<10% OSHA PEL:5 PPM, C ACGIH TLV:5 PPM, C EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: BALANCE OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:SILICIDES, HYDROXIDES, PROPYLENE OXIDE, FLUORINE, WATER REACTIVE MATLS, SILVER PERCHLORATE, CARBON (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:TETRACHLORIDE, PERCHLORIC ACID, 2-AMINOETHANOL, AMMONIUM HYDROXIDE, ETHYLENEDIAMINE, ETHYLENEIMINE, OLEUM, (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:COPPER & ALUMINUM & THEIR ALLOYS, ALKALI METALS, SULFITES. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:VOMIT. CAN CAUSE LUNG DMG. INGEST:BURNS IN MOUTH, PHARYNX & GI TRACT. WEAK FROM FALLING BLOOD (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:PRESS, NAUS, VOMIT, DYSPHAGIA, ABDOM PAIN, CVS COLLAPSE, CONVLS, COMA & DEATH POSS. ASPHYXIA MAY OCCUR FROM(ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:EDEMA OF GLOTTIS. CHRONIC:EROSION OF TEETH, ULCERATION OF NOSE, MOUTH & GUMS, BRONCH. RPTD/PRLNG SKIN CONT (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:MAY CAUSE DERM. TARGET ORGS:SKIN, EYES, LUNGS, RESP SYS. TO BEST OF MFR'S KNOWLEGDE, CHEM, PHYSICAL & TOX (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:OF THIS SUBSTANCE HAS NOT BEEN FULLY INVESTIGATED. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:ARTICLES SUCH AS SHOES & BELTS. INHAL:REMOVE PATIENT TO FRESH AIR. ADMIN APPRVD OXYG SUPPLY IF (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:BRTHG IS DFCLT. ADMIN ARTF RESP/CPR IF BRTHG HAS CEASED. CALL MD. INGEST:IF CONSCIOUS, WASH OUT MOUTH W/ (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:WATER. HAVE CONSCIOUS PERS DRINK SEVERAL GLASSES OF WATER/MILK, REPEATING IF VOMIT. DO NOT INDUCE VOMIT. (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:AIM TO DILUTE ACID 100 TIMES APPROX. SEEK IMMED MED ATTN. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. RTECS #:9999999ZZ Ingred Name:SPILL PROC:COMPLETE. DO NOT EMPTY INTO DRAINS. DO NOT TOUCH SPILLED MATERIAL. RTECS #:9999999ZZ Ingred Name:OTHER PREC:DRY. MANIPULATE UNDER ADEQ FUME HOOD. MAY CORRODE METALLIC SURFS. PROT FROM MOISTURE. DO NOT USE (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:PRESS TO DISPENSE. EMPTY CNTNRS MAY CONTAIN HAZ RESIDUE. HANDLE & OPEN CNTNR W/CARE. DO NOT GET IN EYES, (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:ON SKIN/ON CLTHG. I/A/W GOOD STOR & HNDLG PRACTICES. DO NOT ALLOW SMOKING & FOOD CONSUMPTION WHILE HNDLG.(ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:FOR LAB USE ONLY. RTECS #:9999999ZZ Ingred Name:EYE PROT:& FULL LENGTH FACESHIELD . RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP:CLTHG AS REQD FOR WORKPLACE CNDTNS TO PVNT CONT W/HYDROCHLORIC ACID SOLNS. SUFFICIENT TO PROT (ING 22) RTECS #:9999999ZZ Ingred Name:ING 21:SKIN. HAVE AVAIL & USE AS APPROPRIATE: SUITS, APRONS & BOOTS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:EYE:VAPS, LIQS & MISTS ARE EXTREMELY CORR. BRIEF CONT OF VAPS WILL BE SEVERELY IRRIT. BRIEF CONT OF LIQ/MIST WILL SEVERELY DMG & PRLNG CONT MAY CAUSE PERM INJURY WHICH MAY BE FOLLOWED BY BLINDNE SS. SKIN:CAUSES SEV BURNS. SEV PAIN & BROWNISH/YELLOW STAINS:USUALLY PENETRATES FULL THICKNESS OF SKIN.(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:LESSER EXPOS MAY CAUSE DERM & PHOTOSENSIT. INHAL:MATL IS EXTREMELY DESTRUCT TO TISS OF MUC MEMBS & UPPER RESP TRACT. INHAL MAY BE FATAL AS RSLT OF SPASM, INFLAMM & EDEMA OF LARYNX & BRONCHI, CHEM PNEUM & PULM EDEMA. SYMPS OF EXPOSMAY INCL BURNING SENSATION, COUGH, LARYNGITIS, DYSPNEA, HDCH, NAUS & (ING 6) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE:IMMED FLUSH W/COPIOUS QTYS OF WATER FOR AT LST 30 MINS HOLDING LIDS APART TO ENSURE FLUSHING OF ENTIRE SURF. DO NOT USE CHEM ANTIDOTES. SPEED IS ESSNTL. SEEK IMMED MED ATTN. SKIN:IMMED FLUSH W/PLE NTY OF WATER FOR AT LST 30 MINS WHILE REMOVING CONTAM CLTHG & SHOES. DO NOT USE CHEM ANTIDOTES. SPEED IS ESSNTL. SEEK IMMED MED ATTN. WASH CONTAM CLTHG BEFORE REUSING. DISCARD CONTAM LEATHER (ING 11) ===================== Fire Fighting Measures ===================== Extinguishing Media:USE EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING MATERIALS. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . COOL CNTNG VESSELS W/FLOODING QTYS OF WATER UNTIL WELL AFTER FIRE IS OUT. DO NOT GET WATER INSIDE CNTNR. Unusual Fire/Explosion Hazard:FLAMMABLE/EXPLOSIVE HYDROCARBON GAS MAY BE FORMED UPON CONTACT OF THIS PRODUCT W/METALS. EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR NIOSH/MSHA APPRVD SCBA, RUB BOOTS & HEAVY RUB GLOVES. FULL SUIT. EVACUATE & VENT AREA. COVER W/SODA ASH/LIME. THIS WILL RELS CARBON DIOXIDE, SO USE CAUT. PLACE IN SUITABLE CNTNR & MARK FOR DISP. WASH SPILL SITE AFTER MATL PICK UP IS (ING 15) Neutralizing Agent:SODA ASH OR LIME. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL PLACE AWAY FROM HEATED AREAS, SPKS & FLAME. STORE IN WELL VENTED AREA. STORE AWAY FROM INCOMPAT MATLS. DO NOT WASH DOWN DRAIN. Other Precautions:DO NOT ADD ANY OTHER MATL TO CNTNR. DO NOT BREATHE GAS/FUMES/VAP/SPRAY. IN CASE OF INSUFFICIENT VENT, WEAR SUITABLE NIOSH/MSHA APPRVD RESP EQUIP. KEEP AWAY FROM DIRECT SUNLIGHT/STRONG INCANDESCENT LIG HT. KEEP CNTNR TIGHTLY CLSD & (ING 16) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQD IF HNDLD IN CLSD VENT SYS. WHERE REQD (LEAK, SPILL, OPEN HNDLG OF LIQ) USE NIOSH/MSHA APPRVD CHEM CARTRIDGE RESP FOR GAS <60 PPM. FOR GAS >60 PPM/MIST, USE NIOSH/MSHA APPRVD SCBA/AIR SUPPLIE D RESP, BOTH W/FULL FACEPIECES. Ventilation:USE ONLY IN A CHEMICAL FUME HOOD TO KEEP AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. Protective Gloves:IMPERVIOUS GLOVES (NEOPRENE). Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(ING 20) Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA. APRON, COVERALLS &/OR OTHER RESIST PROT(ING 21) Work Hygienic Practices:WASH WELL AFTER USE. TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. DO NOT WEAR CONTACT LENSES. Supplemental Safety and Health PH(1% SOLN/WATER):<7. MATLS TO AVOID:ANHYDRIDE, BETA-PROPIOLACETONE, VINYL ACETATE, MERCURIC SULFATE, CALCIUM PHOSPHIDE, FORMALDEHYDE, ALKALIES, CARBONATES, BASES, SULFURIC ACID, CHLOROSULFONIC ACID, NITRIC ACID, OXIDIZING AGENTS, CYANIDES, SULFIDES, FLUORIDES, PHOSPHIDES, ACETYLIDES, BROMIDES, CARBIDES, (ING 3) ================== Physical/Chemical Properties ================== HCC:T4 Vapor Density:1.3 pH:SUPDAT Solubility in Water:MISCIBLE Appearance and Odor:COLORLESS FUMING LIQUID W/PUNGENT ODOR. Percent Volatiles by Volume:100V/V ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WILL CORRODE WIDE VARIETY OF METALS. REACTS W/MOST COMMON METALS TO PRDCE HYDROGEN. AMINES, METAL OXIDES, ACETIC(SUDPAT) Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:FIRE DEGRADATION PRODUCTS: HYDROGEN CHLORIDE GAS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . ACCORDING TO ALL APPLICABLE REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.