MALLINCKRODT BAKER INC -- SODIUM CARBONATE ANHYDROUS, 1338 -- -
===================== Product Identification ===================== Product ID:SODIUM CARBONATE ANHYDROUS, 1338 MSDS Date:12/08/1996 FSC:NIIN:Submitter:N EN Status Code:A === Responsible Party === Company Name:MALLINCKRODT BAKER INC Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Info Phone Num:800-582-2537 Emergency Phone Num:908-859-2151 Resp. Party Other MSDS Num.:S3242 Chemtrec Ind/Phone:(800)424-9300 CAGE:70829 === Contractor Identification === Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM CARBONATE CAS:497-19-8 RTECS #:VZ4050000 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT): 4090 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION: INHALATION OF DUST MAY CAUSE IRRITATION TO THE RESPIRATORY TRACT. SYMPTOMS FROM EXCESSIVE INHALATION OF DUST MAY INCLUDE COUGHING AND DIFFICULT BREATHING. EXCESSIVE CONTACT IS KNOWN TO CAUSE DAMAGE TO THE NASAL SEPTUM. INGESTION: SODIUM CARBONATE IS ONLY SLIGHTLY TOXIC, BUT LARGE DOSES MAY BE CORROSIVE TO THE GASTRO-INTESTINAL TRACT WHERE SYMPTOMS MAY INCLUDE SEVERE ABDOMINAL PA IN, VOMITING, DIARRHEA, COLLAPSE AND DEATH. SKIN: EXCESSIVE CONTACT MAY CAUSE IRRITATION WITH BLISTERING AND REDNESS. SOLUTIONS MAY CAUSE SEVERE IRRITATION OR BURNS. (EFTS OF OVEREXP). Effects of Overexposure:HLTH HAZ: EYE: CONTACT MAY BE CORROSIVE TO EYES AND CAUSE CONJUCTIVAL EDEMA AND CORNEAL DESTRUCTION. RISK OF SERIOUS INJURY INCREASES IF EYES ARE KEPT TIGHTLY CLOSED. OTHER SYMPTOMS MAY APPEAR FROM AB SORPTION OF SODIUM CARBONATE INTO THE BLOODSTREAM VIA THE EYES. CHRONIC: PROLONGED OR REPEATED SKIN EXPOSURE MAY CAUSE SENSITIZATION. Medical Cond Aggravated by Exposure:NO INFORMATION FOUND. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTF RESP. IF BREATHING IS DFCLT, GIVE OXYGEN. GET MED ATTN. INGEST: IF SWALLOWED, DO NOT INDUCE VOMIT. GIVE LRG QTIES OF H*2O. NEVER GIVE ANYTHING B Y MOUTH TO AN UNCON PERSON. GET MED ATTN IMMED. SKIN: IMMED FLUSH W/PLENTY OF SOAP & H*2O FOR AT LEAST 15 MIN. REMOVE CONTAMD CLOTHING & SHOES. GET MED ATTN. WASH CLOTHING BEFORE REUSE. THOROUGHLY CLE AN SHOES BEFORE REUSE. EYE: IMMED FLUSH W/PLENTY OF H*2O FOR AT LEAST 15 MIN, LIFTING LOWER & UPPER EYELIDS OCCASIONALLY. GET MED ATTN IMMED. NOTE TO MD: CONSIDER ENDOSCOPY IN ALL SUSPECTED CASES OF SODIUM CARBONATE POISONING. (SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . USE PROTECTIVE CLOTHING AND BREATHING EQUIPMENT APPROP FOR THE SURROUNDING FIRE. Unusual Fire/Explosion Hazard:NOT CONSIDERED AN EXPLOSION HAZARD, BUT SODIUM CARBONATE MAY EXPLODE WHEN APPLIED TO RED-HOT ALUMINUM. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT AS SPECIFIED IN SECTION 8. SPILLS: SWEEP UP AND CONTAINERIZE FOR RECLAMATION OR DISPOSAL. VACUMMING OR WET SWEEPING MAY BE USED TO AVOID DUST DISPERSAL. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CNTNR, STORED IN A COOL, DRY, VENT AREA. PROTECT AGAINST PHYSICAL DAMAGE. ISOLATE FROM INCOMPATIBLE SUBSTANCES. CNTNRS OF THIS MATL MAY BE HAZ WHEN EMPTY SINCE THEY RETAIN PRO D RESIDUCES (DUST, SOLIDS); OBESERV ALL WARNINGS & PRECAUTIONS LISTED FOR PROD. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR CONDITIONS OF USE WHERE EXPOSURE TO DUST/MIST IS APPARENT, A NIOSH APPROVED HALF-FACE DUST/MIST RESPIRATOR MAY BE WORN. FOR EMERGENCIES/INSTANCES WHERE EXPOSURE LEVELS ARE NOT KNOWN, USE A NIOSH A PPROVED FULL-FACE POSITIVE-PRESSURE, NIOSH APPROVED AIR-SUPPLIED RESPIRATOR. WARNING: AIR-PURIFYING RESP DO NOT PROTECT WORKERS IN OXYGEN-DEFICIENT ATMOSPHERE. Ventilation:SYS OF LOC &/GENERAL EXHST IS REC TO KEEP EMPLOYEE EXPOS AS LOW AS POSS. LOC EXHST VENT IS GENERALLY PREFERRED BECAUSE IT CAN CONTROL EMISSIONS OF (SUPDAT) Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES & FULL LENGTH FACESHIELD . Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . WEAR PROTECTIVE GLOVES AND CLEAN BODY-COVERING CLOTHING. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health FIRST AID PROC: PERFORM BLOOD ANALYSIS TO DETERM IF DEHYDRATION, ACIDOSIS/OTHER ELECTROLYTE IMBALANCE OCCURRED. VENT: CONTAM AT ITS SOURCE, PREVENTING DISPERSION OF IT INTO GENERAL WORK AREA. PLEASE R EFER TO ACGIH DOCUMENT, INDUSTRIAL VENTILATION, MANUAL OF REC PRACTICES, MOST RECENT EDITION, FOR DETAILS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:DECOMPOSES Melt/Freeze Pt:=851.C, ######F Vapor Pres:NO INFORMATION FOUND Vapor Density:OTHER INFO Spec Gravity:2.53 pH:OTHER INFO Evaporation Rate & Reference:NO INFORMATION FOUND Solubility in Water:OTHER INFO Appearance and Odor:WHITE POWDER OR GRANULES ODORLESS. Percent Volatiles by Volume:OTHER INFO ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES FLUORINE, ALUMINUM, PHOSPHOROUS PENTOXIDE, SULFURIC ACID, ZINC, LITHIUM, MOISTURE, CALCIUM HYDROXIDE AND 2,4,6-TRINITROTOLUENE. REACTS VIOLENTLY WITH ACIDS TO FORM CARBON DIOXIDE. Stability Condition to Avoid:MOISTURE, HEAT, DUSTING AND INCOMPATIBLES. Hazardous Decomposition Products:OXIDES OF CARBON AND SODIUM OXIDE. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information =================== Toxicological Information:FOR SODIUM CARBONATE: INHALATION RAT LC50: 2300 MG/M3/2H; IRRITATION EYE RABBIT: 50 MG SEVERE; INVESTIGATED AS A MUTAGEN, REPRODUCTIVE EFFECTOR. ===================== Ecological Information ===================== Ecological:ENVIRONMENTAL FATE AND ENVIRONMENTAL TOXICITY: NO INFORMATION FOUND. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING SHOULD BE MANAGED IN APPROP & APPROVED WASTE DISPOSAL FACILITY. PROCESSING, USE/CONTAM OF THIS PROD MAY CHANGE WASTE MANAGEMENT OPTIONS. STATE & LOCAL D ISPOSAL REGULATIONS MAY DIFFER FROM FED DISPOSAL REGULATIONS. DISPOSE OF CNTNR & UNUSED CONTENTS I/A /W/FED, STATE & LOCAL REQUIREMENTS. =================== MSDS Transport Information =================== Transport Information:NOT REGULATED. ===================== Regulatory Information ===================== SARA Title III Information:FEDERAL, STATE & INTERNATIONAL REGULATIONS - PART 1 INGREDIENT SODIUM CAARBONATE (497-19-8): SARA 302: RQ, TPQ: NO. SARA 313: LIST CHEMICAL CATG. NO. Federal Regulatory Information:AUSTRALIAN HAZCHEM CODE: NO INFORMATION FOUND. POISON SCHEDULE: S5. WHMIS: THIS MSDS HAS BEEN PREPARED ACCORDING TO THE HAZARD CRITERIA OF THE CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE MSDS CONTAI NS ALL OF THE INFORMATION REQUIRED BY THE CPR. State Regulatory Information:REGULATORY INFORMATION: CHEMICAL INVENTORY STATUS - PART 1: INGREDIENT SODIUM CARBONATE (497-19-8) TSCA, EC, JAPAN, AUSTRALIA. CHEMICAL INVENTORY STATUS-PART 2 INGREDIENT SODIUM CARBONATE (497-19-8) C ANADA: KOREA, DSL, PHIL. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.