DEVOE COATINGS CO -- 369B3501, DEVTHANE 369 ALIPHATIC URETHANE (SUPP DATA) -- 8010-01-306-0742
===================== Product Identification ===================== Product ID:369B3501, DEVTHANE 369 ALIPHATIC URETHANE (SUPP DATA) MSDS Date:04/16/1992 FSC:8010 NIIN:01-306-0742 === Responsible Party === Company Name:DEVOE COATINGS CO Address:4000 DUPONT CIRCLE City:LOUISVILLE State:KY ZIP:40207 Country:US Info Phone Num:502-897-9861 Emergency Phone Num:800-424-9300(CHEMTREC) CAGE:1HK86 === Contractor Identification === Company Name:DEVOE COATINGS CO Address:4000 DUPONT CIRCLE Box:7600 City:LOUISVILLE State:KY ZIP:40207-4802 Country:US Phone:502-897-9861 CAGE:1HK86 ============= Composition/Information on Ingredients ============= Ingred Name:ACRYLIC RESIN Fraction by Wt: 30% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE) (CERCLA). VP:13. LD50:(ORAL,RAT) 14 GM/KG. CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 10% OSHA PEL:150 PPM ACGIH TLV:150 PPM;200 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER;(PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE). VP:3.7. LD50:(ORAL,RAT)8.5 G/KG. CAS:108-65-6 RTECS #:AI8925000 Fraction by Wt: 20% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:PROPANE, 1,2-EPOXY-; (PROPYLENE OXIDE) (SARA 302/313) (CERCLA). VP:440. CAS:75-56-9 RTECS #:TZ2975000 Fraction by Wt: <0.5% OSHA PEL:100 PPM ACGIH TLV:20 PPM EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE). LD50:(ORAL,RAT) >24,000 MG/KG. CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 35% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:XYLENE (SARA 313) (CERCLA). VP:6. LD50:(ORAL,RAT) >5 GM/KG. CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: <5% OSHA PEL:100 PPM ACGIH TLV:100 PPM;150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:VOLATILE ORGANIC COMPOUNDS: 456.95 G/L. RTECS #:9999999VO Ingred Name:EXPLO HAZ:MAY SPREAD LONG DISTS & BEYOND CLSD DOORS. DUE TO PRESS BUILD-UP, CLSD CNTNRS EXPOS TO EXTREME HEAT MAY(ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:EXPLODE. NEVER USE WELDING/CUTTING TORCH ON/NEAR CNTNR (EVEN EMPTY) AS PROD/ITS RESIDUE MAY IGNITE. DURING(ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:INGEST:CONSULT MD IMMED. DO NOT INDUCE VOMIT. ASPIR OF VOMITUS CAN CAUSE CHEM PNEUM WHICH CAN BE FATAL. RTECS #:9999999ZZ Ingred Name:SPILL PROC:ABSORBENT & NON-SPARKING TOOLS. STORE IN CLOSED CONTAINER UNTIL PROPERLY DISPOSED OF. RTECS #:9999999ZZ Ingred Name:OTHER PREC:BUILD-UP OF VAPS BY MAINTAINING CONTINUOUS FLOW OF FRESH AIR. DO NOT STORE >120F OR NEAR FIRE/OPEN (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:FLAME. STORE LG QTYS IN BLDGS TO COMPLY W/OSHA 1910.106. KEEP CNTNR CLSD WHEN NOT IN USE. DO NOT TRANSFER(ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:CONTENTS TO BOTTLES/OTHER UNLABELLED CNTNRS. DO NOT REUSE EMPTY CNTNRS. IF THIS MATL IS PART OF A TWO- (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:COMPONENT PROD, THEN MIXTURE OF BASE & CONVERTER PORTIONS WILL HAVE HAZS OF BOTH COMPONENTS. RTECS #:9999999ZZ Ingred Name:RESP PROT:MSHA APPRVD CHEM/MECH FILTER DESIGNED TO REMOVE COMBINATION OF PARTICULATES & VAP. WHEN USED IN (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:CONFINED AREAS, WEAR NIOSH/MSHA APPRVD AIR SUPPLY RESPS/USE HOODS. USE NIOSH/MSHA APPRVD RESP WHEN FLAME (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:CUTTING, WELDING, BRAZING & SANDING MATERIAL COATED W/THIS PRODUCT. RTECS #:9999999ZZ Ingred Name:VENT:STDS IN MIXING, APPLICATION & CURING AREAS & TO REMOVE SANDING DUSTS OF DRIED COATINGS & DECOMP PRODS (ING 21) RTECS #:9999999ZZ Ingred Name:ING 20:DURING WELDING & FLAME CUTTING ON SURFS COATED W/THIS PROD. VAPS MAY SPREAD LONG DISTS. PVNT BUILD-UP BY (ING 22) RTECS #:9999999ZZ Ingred Name:ING 21:REMOVING HEAVY SOLVENT VAPORS FROM LOWER LEVELS OF WORK AREA. ELIMINATE ALL IGNITION SOURCES. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:IRRIT OF RESP TRACT; HDCH, NAUS, DIZZ, WEAK & FATG. EXTREME EXPOS CAN RSLT IN UNCON & EVEN RESP ARREST. SKIN/EYE CONT:CAUSES EYE & SKIN IRRIT. MAY BE HARMFUL IF ABSORBEED THRU SKIN. INGEST :CAN CAUSE STOM &/OR INTEST IRRIT, NAUS, VOMIT & DIARR. CHRONIC:RPTS HAVE ASSOC RPTD & PRLNG OCCUP (EFTS OF OVEREXP) Explanation of Carcinogenicity:PROPYLENE OXIDE:IARC MONOGRAPHS, SUPP, VOL 60, PG 181, 1994:GRP 2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC TO(SUPDAT) Effects of Overexposure:HLTH HAZ:OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG. PRLNG/RPTD BRTHG OF SPRAY MIST &/OR SANDING DUST OVER PERIOD OF YRS MAY CAUSE DUST DISEASE OF LUNGS. NOTICE:INTENTIONAL MISUSE BY DELIB CONC & IN HALING CONTENTS MAY BE HARMFUL/FATAL. WARNING:THIS PROD MAY CONTAIN CHEM KNOWN TO STATE OF CALIFORNIA TO CAUSE (SUPDAT) Medical Cond Aggravated by Exposure:NONE, WHEN USED I/A/W SAFE HANDLING & USE INFORMATION. ======================= First Aid Measures ======================= First Aid:INHAL:IF YOU EXPER DFCLTY IN BRTHG, LEAVE AREA TO OBTAIN FRESH AIR. IF CONTINUED DFCLTY IS EXPERIENCED, SUMMON MED ASSISTANCE IMMED. IF BRTHG CEASES, RESTORE USING APPRVD CPR TECHNIQUES & SUMMON MED H ELP IMMED. EYES:FLUSH IMMED W/LG AMTS OF WATER FOR AT LST 15 MINS. GET MED ASSISTANCE. SKIN:WASH AFFECTED AREAS W/SOAP & WATER. REMOVE SOILED CLTHG. GET MED ASSISTANCE IF IRRIT PERSISTS. (ING 11) ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:80.0F,26.7C Lower Limits:1% Extinguishing Media:IN CASE OF FIRE USE CO*2, DRY CHEMICAL, FOAM OR OTHER NFPA APPROVED METHOD FOR TREATING A CLASS B FIRE. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . SUMMON PROFESSIONAL FIREFIGHTERS. WATER SPRAY MAY BE INEFT. IF WATER IS USED, FOG NOZZ ARE PREF. IF(SUPDAT) Unusual Fire/Explosion Hazard:FLAMM LIQ-CLASS 1C. KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT, ELEC EQUIP, SPKS & FLAME. VAPS MAY CAUSE FLASH FIRE. VAPS MAY IGNITE EXPLOSIVELY. VAPS (ING 8) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT (FLAMES, HOT SURFS & ELEC, STATIC/FRICTIONAL SPKS). PVNT BRTHG OF VAPS. VENTILATE AREA. BEFORE ATTEMPTING CLEAN-UP, REFER TO HAZ CAUT INFO IN OTHER SECTIONS OF THIS MSDS. C ONTAIN SPILLED MATL & REMOVE W/INERT (ING 12) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:DO NOT BREATHE VAPS, SPRAY MIST/SANDING DUST. DO NOT GET ON SKIN/IN EYES. KEEP AWAY FROM HEAT, SPKS & FLAMES. DO NOT SMOKE. OBSERVE ALL APPLIC PRECS. Other Precautions:EXTING ALL PILOT LIGHTS & TURN OFF ALL SOURCES OF IGNIT INCL HEATERS, FANS & OTHER NON-EXPLO-PROOF ELEC EQUIP, DURING USE & UNTIL ALL VAPS ARE GONE. VAPS MAY IGNITE EXPLOSIVELY. VAPS MAY SPREAD LONG D ISTS & BEYOND CLSD DOORS. PVNT (ING 13) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN SPRAY APPLIED IN OUTDOOR/OPEN AREAS & DURING SANDING/GRINDING OPERATIONS, USE NIOSH/MSHA APPRVD MECH FILTER RESP TO REMOVE SOLID AIRBORNE PARTICLES OF OVERSPRAY & SANDING DUST. WHEN USED IN RESTR ICTED VENT AREAS, WEAR NIOSH/ (ING 17) Ventilation:PROVIDE GEN DILUTION/LOC EXHST VENT IN VOL & PATTERN TO KEEP AIR CONTAM CONC BELOW CURRENT APPLIC SFTY & HLTH (ING 20) Protective Gloves:SOLVENT IMPERMEABLE GLOVES. Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS . Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . SOLV IMPERMEABLE CLTHG & BOOTS TO (SUPP DATA) Work Hygienic Practices:REMOVE & WASH SOILED CLOTHING BEFORE REUSE. WASH HANDS BEFORE EATING OR SMOKING. Supplemental Safety and Health MFR'S TRADE NAME/PART NO:GLOSS WHITE BASE. FIRE FIGHT PROC:EXPOS TO FIRE/EXTREME HEAT, WATER SHOULD BE USED TO COOL CLSD CNTNRS & PVNT PRESS BUILD UP/POSS AUTO-IGNIT. EXPLAN OF CARCIN:BE CARCIN. EFTS OF OVEREXP:CANCER, BIRTH DEFECTS/OTHER REPRO HARM (PROPOSITION 65). OTHER PROT EQUIP:PREVENT SKIN CONTACT ARE REC. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>94F,>34C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:1.4 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:49.38 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT W/STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:MAY CAUSE TOXIC FUMES WHEN HEATED TO DECOMPOSITION. FUMES MAY CONTAIN CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF I/A/W LOCAL, STATE & FEDERAL REGULATIONS. INCINERATE ONLY IN APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINERS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.