MALLINCKRODT CHEMICAL INC -- SODIUM BORATE -- 6810-00N082270
===================== Product Identification ===================== Product ID:SODIUM BORATE MSDS Date:10/15/1985 FSC:6810 NIIN:00N082270 === Responsible Party === Company Name:MALLINCKRODT CHEMICAL INC Box:800 City:PARIS State:KY ZIP:40362 Country:US Info Phone Num:314-539-1600 Emergency Phone Num:314-539-1600; 314-982-5000 CAGE:23104 === Contractor Identification === Company Name:MALLINCKRODT CHEMICAL WORKS LTD Address:600 DELMAR City:POINTE CLAIRE QUE CAN H9R CAGE:23104 Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM BORATE, DECAHYDRATE; (HYDRATE) CAS:1303-96-4 RTECS #:VZ2275000 OSHA PEL:10 MG/M3 ACGIH TLV:5 MG/M3 Ingred Name:BORIC ACID, DISODIUM SALT; (SODIUM TETRABORATE, ANHYDROUS) (BORAX); (ANHYDROUS) CAS:1330-43-4 RTECS #:ED4588000 OSHA PEL:10 MG/M3 ACGIH TLV:1 MG/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL, RAT) 2660 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHAL: MAY CAUSE IRRIT TO RESPIRATORY TRACT, COUGHING, NAUSEA & VOMITING. INGEST: MAY CAUSE NAUSEA, VOMITING, DIARRHEA, MUSCULAR SPASMS, DULLNESS, LETHARGY, CIRCULATORY DEPRESS, CNS DEPRESS, SHOCK, KI DNEY DAMAGE, COMA & DEATH. ESTIMATED LETHAL DOSE 15-20 GRAMS. SKIN CONTACT: MAY CAUSE IRRIT. MAY BE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: ABSORBED THRU SKIN, ESP DAMAGED SKIN W/SYMPS PARALLELING INGEST. EYE CONTACT: MAY CAUSE IRRIT, REDNESS & PAIN. CHRONIC: PRLNGD/RPTD INGEST OR SKIN ABSORPTION MAY CAUSE ANOREXIA, WEIGHT LOSS, VOMITING, MILD DIARRHEA, SKIN RASH, CONVULSIONS & ANEMIA. TOXICITY DATA: MUTATION REFERENCES. REPRODUCTION EFTS CITED. Medical Cond Aggravated by Exposure:NO INFORMATION FOUND. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. GET MED ATTN FOR ANY BRTHG DFCLTY. INGEST: IF SWALLOWED, INDUCE VOMIT IMMED BY GIVING 2 GLASSES OF WATER & STICKING FINGER DOWN THROAT. NEVER GIVE ANYTHING BY MOUTH IF UNCO N. CALL MD IMMED. SKIN: IN CASE OF CNTCT, IMMED FLUSH SKIN W/PLENTY OF WATER FOR AT LST 15 MIN WHILE REMOVING CONTAMD CLTHG & SHOES. CALL MD. EYES: WASH EYES W/PLENTY OF WATER FOR AT LST 15 (SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE A FIRE OR EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. CLEAN-UP PERSONNEL MAY REQUIRE NIOSH APPROVED RESPIRATORY PROTECTION FROM DUST. SPILLS: SWEEP UP & CONTAINERIZE FOR RECLAMATION OR DISPOSAL. VACUUMING OR WET SWEEPING MAY BE USED TO AVOID DUST DISPERSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER, STORED IN A COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL DAMAGE. Other Precautions:AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID BREATHING DUST. KEEP CONTAINER CLOSED. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV IS EXCEEDED, A NIOSH APPRVD DUST/MIST RESP W/CHEM GOGGS MAY BE WORN, IN GEN, UP TO TEN TIMES THE TLV. CONSULT RESP SUPPLIER FOR LIMITATIONS. ALTERNATIVELY, NIOSH APPRVD SUPPLIED AIR FULL FACEPI ECE RESP OR AIRLINED HOOD MAY BE WORN. Ventilation:SYS OF LOC &/OR GEN EXHST RECOMD TO KEEP EMPLOYEE EXPOS BELOW AIRBORNE EXPOS LIMS. LOC EXHST VENT IS GEN PREF (SUPDAT) Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . WEAR IMPERVIOUS PROT CLTHG INCLUDING BOOTS, LAB COAT, APRON OR COVERALLS. Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING WITH THIS MATERIAL. Supplemental Safety and Health BP: LOSES WATER @ 608F,320C. FIRST AID PROC: MIN, LIFTING LOWER & UPPER EYELIDS OCCASNLY. GET MED ATTN IMMED. VENT: BECAUSE IT CAN CTL EMISSIONS OF CONTAMINANT AT ITS SOURCE, PREVENTING DISPERSION OF IT INTO GEN WORK AREA. REFER TO ACGIH, "INDUS VENT, A MANUAL OF RECOMD PRACTS," MOST RECENT EDITION, FOR DETAILS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:SUPDAT Melt/Freeze Pt:M.P/F.P Text:167F,75C Spec Gravity:1.73 Solubility in Water:6 G/100G WATER Appearance and Odor:GREY, BLUE OR GREEN CRYSTALS; ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, ALKALOIDS AND METALLIC SALTS. Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE AND STORAGE. Hazardous Decomposition Products:EMITS TOXIC FUMES OF SODIUM OXIDE WHEN HEATED TO DECOMPOSITION. ==================== Disposal Considerations ==================== Waste Disposal Methods:ENSURE COMPLIANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.