DEVOE COATINGS CO -- UNIVERSAL METAL PRIMER BROWN P40, 440S0100 -- 8010-00N054657
===================== Product Identification ===================== Product ID:UNIVERSAL METAL PRIMER BROWN P40, 440S0100 MSDS Date:10/19/1990 FSC:8010 NIIN:00N054657 === Responsible Party === Company Name:DEVOE COATINGS CO Address:4000 DUPONT CIRCLE City:LOUISVILLE State:KY ZIP:40207 Country:US Info Phone Num:502-897-9861 Emergency Phone Num:800-424-9300 (CHEMTREC) CAGE:1HK86 === Contractor Identification === Company Name:DEVOE COATINGS CO Address:4000 DUPONT CIRCLE Box:7600 City:LOUISVILLE State:KY ZIP:40207-4802 Country:US Phone:502-897-9861 CAGE:1HK86 ============= Composition/Information on Ingredients ============= Ingred Name:ALKYD RESIN Fraction by Wt: 10% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SILICA GEL; (AMORPHOUS SILICA) CAS:63231-67-4 RTECS #:VV7322000 Fraction by Wt: <5% OSHA PEL:80 MG/M3 / % SIO2 ACGIH TLV:10 MG/M3 Ingred Name:BENZENE, ETHYL-; (ETHYL BENZENE) (SARA 313). VP:10 CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 10% OSHA PEL:100 PPM ACGIH TLV:100 PPM/125 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:IRON (III) OXIDE CAS:1309-37-1 RTECS #:NO7400000 Fraction by Wt: 5% OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5 MG(FE)/M3FUME, B2 Ingred Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (MAGNESIUM SILICATE) CAS:14807-96-6 RTECS #:WW2710000 OSHA PEL:0.2 FIBERS/CC ACGIH TLV:0.2 FIBER/CC, A1 Ingred Name:2-PENTANONE, 4-METHYL-; (METHYL ISOBUTYL KETONE) (SARA 313) (CERCLA). LD50:(ORAL,RAT) 1.6-3.2 GM/KG. VP:15 CAS:108-10-1 RTECS #:SA9275000 Fraction by Wt: 30% OSHA PEL:100 PPM ACGIH TLV:50 PPM/75 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BUTYL ALCOHOL (SARA 313) (CERCLA). LD50:(ORAL,RAT) 2.5 GM/KG. VP:4.2 CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: <5% OSHA PEL:100 PPM ACGIH TLV:S, C 50 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TOLUENE (SARA 313) (CERCLA). LD50:(ORAL,RAT) >5 GM/KG. VP:24 CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 10% OSHA PEL:200 PPM; Z-2 ACGIH TLV:S, 50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:VINYL RESIN CAS:25086-48-0 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:XYLENE (SARA 313) (CERCLA). LD50:(ORAL,RAT) >5 GM/KG. VP:6 CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: <5% OSHA PEL:100 PPM ACGIH TLV:100 PPM/150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CHROMIC ACID, ZINC SALT; (ZINC CHROMATE). LD50:(ORAL,RAT) >24 GM/KG. CAS:13530-65-9 RTECS #:GB3290000 Fraction by Wt: 5% OSHA PEL:0.1 MG(CRO3)/M3 ACGIH TLV:0.01 MG(CR)/M3, A1 Ingred Name:ZINC OXIDE (SARA 313) (CERCLA). LD50:(ORAL,RAT) >24 GM/KG CAS:1314-13-2 RTECS #:ZH4810000 Fraction by Wt: 5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:VOLATILE ORGANIC COMPOUND:598.61 (GRAMS/LITER) RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN. ZINC OXIDE FUME MY RSLT FROM (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:COMBUSTION. TLV & PEL FOR ZN*O FUME IS 5 MG/MG. RTECS #:9999999ZZ Ingred Name:EXPLAN OF CARCIN:RPT ON CARCINS, 1994:KNOWN TO BE CARCIN. ANIMAL LUNGS. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:DUST DISEASE OF LUNGS. NOTICE:INTENTIONAL MISUSE BY DELIB CONCENTRATING & INHALING CONTENTS (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:MAY BE HARMFUL OR FATAL. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:PHYS IMMED. DO NOT INDUCE VOMIT. ASPIR OF VOMITUS CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. RTECS #:9999999ZZ Ingred Name:SPILL PROC:ABSORB & NON-SPK TOOLS. STORE IN CLSD CNTNR UNTIL PROPERLY DISPOSED OF. RTECS #:9999999ZZ Ingred Name:OTHER PREC:>120F/NEAR FIRE/OPEN FLAME. STORE LG QTYS IN BUILDING TO COMPLY W/OSHA 1910.106. KEEP CNTNR CLSD WHEN(ING 22) RTECS #:9999999ZZ Ingred Name:ING 21:NOT IN USE. DO NOT TRANSFER CONTENTS TO BOTTLE/OTHER UNLBLD CNTNRS. FOR MORE INFORMATION CONT NEHC . RTECS #:9999999ZZ Ingred Name:VENT:& HLTH STDS IN MIXING, APPLIC & CURING AREAS & TO REMOVE SANDING DUST OF DRIED COATINGS & DECOMP PRODS (ING 24) RTECS #:9999999ZZ Ingred Name:ING 23:DURING WELDING & FLAME CUTTING ON SURFS COATED W/THIS PROD. VAPS MAY SPREAD LONG DIST. PVNT BUILD-UP BY(ING 25) RTECS #:9999999ZZ Ingred Name:ING 24:REMOVING HEAVY SOLV VAPS FROM LOWER LEVELS OF WORK AREA. ELIM ALL IGNIT SOURCES. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS 6,7,8,10 & 12 Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:TOLUENE APPEARS ON NAVY LISTING OF OCCUP CHEM REPROD HAZS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO . ACUTE:INHAL:IRRIT OF RESP TRACT; HDCH, NAUS, DIZZ, WEAK & FATG. EXTREME EXPOS CAN RSLT IN UNCON & EVEN RESP ARREST. SKIN OR EYE (EFTS OF OVEREXP) Explanation of Carcinogenicity:ZINC CHROMATE:IARC MONO SUPP ON EVAL OF CARCIN RISK OF CHEMS TO MAN, VOL 49, PG 49, 1990:GROUP 1. NTP 7TH ANNUAL(ING 16) Effects of Overexposure:HLTH HAZ:CONT:CAUSES IRRITATION. MAY BE HARMFUL IF ABSORBED THRU SKIN. INGEST:CAN CAUSE STOM AND/OR INTESTINAL IRRIT, NAUS, VOMIT & DIARR. CHRONIC:RPTS HAVE ASSOC RPTD & PRLNGD OCCUP OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG. PRLNGD/RPTD BRTHG OF SPRAY MIST AND/OR SANDING DUST OVER PERIOD OF YRS MAY CAUSE (ING 17) Medical Cond Aggravated by Exposure:NONE, WHEN USED I/A/W SAFE HANDLING AND USE INFORMATION. ======================= First Aid Measures ======================= First Aid:INGEST:IF DFCLTY IN BRTHG, LEAVE AREA TO OBTAIN FRESH AIR. IF CONTINUED DFCLTY IS EXPERIENCED, SUMMON MED ASSISTANCE IMMED. IF BRTHG CEASES, RESTORE USING APPRVD CPR TECHNIQUES SUMMON MED HELP IMMED. EYE:FLUSH IMMED W/LG AMTS OF WATER FOR @ LST 15 MINS. GET MED ASSISTANCE. SKIN:WASH AFFECTED AREAS W/SOAP & WATER. REMOVE SOILED CLTHG. GET MED ASSISTANCE IF IRRIT PERSISTS. INGEST:CONSULT (ING 19) ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:65.0F,18.3C Lower Limits:1% Extinguishing Media:CO*2 DRY CHEMICAL, OR OTHER CLASS B FIRE. Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZ PREF. IF EXPOS TO FIRE/EXTREME HEAT, WATER SHOULD BE(SUPDAT) Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT, ELEC EQUIP, SPKS & FLAME. VAPS MAY CAUSE FLASH FIRE. VAPS MAY IGNITE EXPLO. VAPS MAY SPREAD LONG DIST & (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT (FLAMES, HOT SURF, & ELEC, STATIC/FRICTIONAL SPKS). PVNT BRTHG OF VAPS. VENTILATE AREA. BEFORE ATTEMTPING CLEAN-UP, REFER TO HAZ CAUTION INFO IN OTHER SECTIONS OF THIS MSDS . CONTAIN SPILLED MATL & REMOVE W/INERT(ING 20) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPKS & FLAMES. DO NOT SMOKE. VAPS MAY IGNITE EXPLOSIVELY. VAPS MAY SPREAD LONG DIST & BEYOND CLSD DOORS. Other Precautions:EXTING ALL PILOT LIGHT & TURN OFF ALL SOURCES OF IGNIT INCL HEATERS, FANS & OTHER NON-EXPLO-PROOF ELEC EQUIP, DURING USE & UNTIL ALL VAPS ARE GONE. PVNT BUILD-UP OF VAPS BY MAINTAINING CONTINUOUS FLOW OF FRESH AIR. DO NOT STORE (ING 21) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . FOR MORE SPECIFIC INFORMATION ON RESPIRATORS CONTACT NEHC . Ventilation:PROVIDE GEN DILUTION/LOC EXHAUST VENT IN VOL & PATTERN TO KEEP AIR CONTAMINANT CONC BELOW CURRENT APPLIC SFTY (ING 23) Protective Gloves:SOLVENT IMPERMEABLE GLOVES. Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . SOLV IMPERMEABLE CLTHG & BOOTS TO PVNT SKIN CONT. DO NOT GET ON SKIN. Work Hygienic Practices:KEEP AWAY FROM FEED & FOOD PRODS. REMOVE & WASH SOILED CLTHG BEFORE REUSE. WASH HANDS BEFORE EATING OR SMOKING. Supplemental Safety and Health FIRE FIGHT PROC:USED TO COOL CLSD CNTNRS & PVNT PRESS BUILD UP/POSS AUTO-IGNIT. EXPLO HAZ:BEYOND CLSD DOORS. DUE TO PRESS BUILD-UP, CLSD CNTNRS EXPOS TO EXTREME HEAT MAY EXPLODE. NEVER USE WELDING/CUT TING TORCH ON/NEAR CNTNR (EVEN EMPTY) AS PROD/ITS RESIDUE MAY IGNITE. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS(ING 14) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>232F,>111C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:1.12 Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:NOT KNOWN Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:72.16 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:MAY CAUSE TOXIC FUMES WHEN HEATED TO DECOMP. FUMES MAY CONTAIN CO, CO*2, ZINC & CHROMATE CMPDS, CHLORINE OR HCL. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF I/A/W LOCAL, STATE AND FEDERAL REGULATIONS. INCINERATE ONLY IN APPRVD FACILITY. DO NOT INCINERATE CLOSED CONTAINERS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.